Gast ::
| Hauptseite > Publikationsdatenbank > Exploring Aliovalent Substitutions in the Lithium Halide Superionic Conductor Li<sub>3– x</sub>In<sub>1– x</sub>Zr<sub>x</sub>Cl<sub>6</sub> (0 ≤ x ≤ 0.5) > print |
| Hauptseite > Publikationsdatenbank > Exploring Aliovalent Substitutions in the Lithium Halide Superionic Conductor Li<sub>3– x</sub>In<sub>1– x</sub>Zr<sub>x</sub>Cl<sub>6</sub> (0 ≤ x ≤ 0.5) > print |
| 001 | 903325 | ||
| 005 | 20240712113049.0 | ||
| 024 | 7 | _ | |a 10.1021/acs.chemmater.1c01348 |2 doi |
| 024 | 7 | _ | |a 0897-4756 |2 ISSN |
| 024 | 7 | _ | |a 1520-5002 |2 ISSN |
| 024 | 7 | _ | |a 2128/29390 |2 Handle |
| 024 | 7 | _ | |a altmetric:107285803 |2 altmetric |
| 024 | 7 | _ | |a WOS:000665651400048 |2 WOS |
| 037 | _ | _ | |a FZJ-2021-05019 |
| 082 | _ | _ | |a 540 |
| 100 | 1 | _ | |a Helm, Bianca |0 P:(DE-HGF)0 |b 0 |
| 245 | _ | _ | |a Exploring Aliovalent Substitutions in the Lithium Halide Superionic Conductor Li3– xIn1– xZrxCl6 (0 ≤ x ≤ 0.5) |
| 260 | _ | _ | |a Washington, DC |c 2021 |b American Chemical Society |
| 336 | 7 | _ | |a article |2 DRIVER |
| 336 | 7 | _ | |a Output Types/Journal article |2 DataCite |
| 336 | 7 | _ | |a Journal Article |b journal |m journal |0 PUB:(DE-HGF)16 |s 1638963885_20054 |2 PUB:(DE-HGF) |
| 336 | 7 | _ | |a ARTICLE |2 BibTeX |
| 336 | 7 | _ | |a JOURNAL_ARTICLE |2 ORCID |
| 336 | 7 | _ | |a Journal Article |0 0 |2 EndNote |
| 520 | _ | _ | |a In recent years, ternary halides Li3MX6 (M = Y, Er, In; X = Cl, Br, I) have garnered attention assolid electrolytes due to their wide electrochemical stability window and favorable roomtemperatureconductivities. In this material class, the influences of iso- or aliovalentsubstitutions are so far rarely studied in-depth, despite this being a common tool for correlatingstructure and transport properties. In this work, we investigate the impact of Zr substitution onthe structure and ionic conductivity of Li3InCl6 (Li3-xIn1-xZrxCl6 with 0 ≤ x ≤ 0.5) using acombination of neutron diffraction, nuclear magnetic resonance and impedance spectroscopy.Analysis of high-resolution diffraction data shows the presence of an additional tetrahedrallycoordinated lithium position together with cation site-disorder, both of which have not beenreported previously for Li3InCl6. This Li+ position and cation disorder lead to the formation ofa three-dimensional lithium ion diffusion channel, instead of the expected two-dimensionaldiffusion. Upon Zr4+ substitution, the structure exhibits non-uniform volume changes alongwith an increasing number of vacancies, all of which lead to an increasing ionic conductivity inthis series of solid solutions |
| 536 | _ | _ | |a 1221 - Fundamentals and Materials (POF4-122) |0 G:(DE-HGF)POF4-1221 |c POF4-122 |f POF IV |x 0 |
| 536 | _ | _ | |a EProFest - Evaluation von Prozessen zur Produktion von Festkörperbatteriekomponenten (13XP0346B) |0 G:(BMBF)13XP0346B |c 13XP0346B |x 1 |
| 588 | _ | _ | |a Dataset connected to CrossRef, Journals: juser.fz-juelich.de |
| 700 | 1 | _ | |a Schlem, Roman |0 P:(DE-HGF)0 |b 1 |
| 700 | 1 | _ | |a Wankmiller, Björn |0 P:(DE-HGF)0 |b 2 |
| 700 | 1 | _ | |a Banik, Ananya |0 P:(DE-HGF)0 |b 3 |
| 700 | 1 | _ | |a Gautam, Ajay |0 P:(DE-HGF)0 |b 4 |
| 700 | 1 | _ | |a Ruhl, Justine |0 P:(DE-HGF)0 |b 5 |
| 700 | 1 | _ | |a Li, Cheng |0 P:(DE-Juel1)172659 |b 6 |
| 700 | 1 | _ | |a Hansen, Michael Ryan |0 0000-0001-7114-8051 |b 7 |
| 700 | 1 | _ | |a Zeier, Wolfgang |0 P:(DE-Juel1)184735 |b 8 |e Corresponding author |
| 773 | _ | _ | |a 10.1021/acs.chemmater.1c01348 |g Vol. 33, no. 12, p. 4773 - 4782 |0 PERI:(DE-600)1500399-1 |n 12 |p 4773 - 4782 |t Chemistry of materials |v 33 |y 2021 |x 0897-4756 |
| 856 | 4 | _ | |u https://juser.fz-juelich.de/record/903325/files/acs.chemmater.1c01348.pdf |y Restricted |
| 856 | 4 | _ | |y Published on 2021-06-08. Available in OpenAccess from 2022-06-08. |u https://juser.fz-juelich.de/record/903325/files/Helm1.pdf |
| 909 | C | O | |o oai:juser.fz-juelich.de:903325 |p openaire |p open_access |p VDB |p driver |p dnbdelivery |
| 910 | 1 | _ | |a Forschungszentrum Jülich |0 I:(DE-588b)5008462-8 |k FZJ |b 8 |6 P:(DE-Juel1)184735 |
| 913 | 1 | _ | |a DE-HGF |b Forschungsbereich Energie |l Materialien und Technologien für die Energiewende (MTET) |1 G:(DE-HGF)POF4-120 |0 G:(DE-HGF)POF4-122 |3 G:(DE-HGF)POF4 |2 G:(DE-HGF)POF4-100 |4 G:(DE-HGF)POF |v Elektrochemische Energiespeicherung |9 G:(DE-HGF)POF4-1221 |x 0 |
| 914 | 1 | _ | |y 2021 |
| 915 | _ | _ | |a DBCoverage |0 StatID:(DE-HGF)0200 |2 StatID |b SCOPUS |d 2021-01-27 |
| 915 | _ | _ | |a DBCoverage |0 StatID:(DE-HGF)0160 |2 StatID |b Essential Science Indicators |d 2021-01-27 |
| 915 | _ | _ | |a DBCoverage |0 StatID:(DE-HGF)1160 |2 StatID |b Current Contents - Engineering, Computing and Technology |d 2021-01-27 |
| 915 | _ | _ | |a DBCoverage |0 StatID:(DE-HGF)0600 |2 StatID |b Ebsco Academic Search |d 2021-01-27 |
| 915 | _ | _ | |a Embargoed OpenAccess |0 StatID:(DE-HGF)0530 |2 StatID |
| 915 | _ | _ | |a JCR |0 StatID:(DE-HGF)0100 |2 StatID |b CHEM MATER : 2019 |d 2021-01-27 |
| 915 | _ | _ | |a IF >= 5 |0 StatID:(DE-HGF)9905 |2 StatID |b CHEM MATER : 2019 |d 2021-01-27 |
| 915 | _ | _ | |a WoS |0 StatID:(DE-HGF)0113 |2 StatID |b Science Citation Index Expanded |d 2021-01-27 |
| 915 | _ | _ | |a DBCoverage |0 StatID:(DE-HGF)0150 |2 StatID |b Web of Science Core Collection |d 2021-01-27 |
| 915 | _ | _ | |a Peer Review |0 StatID:(DE-HGF)0030 |2 StatID |b ASC |d 2021-01-27 |
| 915 | _ | _ | |a DBCoverage |0 StatID:(DE-HGF)1150 |2 StatID |b Current Contents - Physical, Chemical and Earth Sciences |d 2021-01-27 |
| 915 | _ | _ | |a DBCoverage |0 StatID:(DE-HGF)0300 |2 StatID |b Medline |d 2021-01-27 |
| 915 | _ | _ | |a Nationallizenz |0 StatID:(DE-HGF)0420 |2 StatID |d 2021-01-27 |w ger |
| 915 | _ | _ | |a DBCoverage |0 StatID:(DE-HGF)0199 |2 StatID |b Clarivate Analytics Master Journal List |d 2021-01-27 |
| 920 | 1 | _ | |0 I:(DE-Juel1)IEK-12-20141217 |k IEK-12 |l Helmholtz-Institut Münster Ionenleiter für Energiespeicher |x 0 |
| 980 | 1 | _ | |a FullTexts |
| 980 | _ | _ | |a journal |
| 980 | _ | _ | |a VDB |
| 980 | _ | _ | |a UNRESTRICTED |
| 980 | _ | _ | |a I:(DE-Juel1)IEK-12-20141217 |
| 981 | _ | _ | |a I:(DE-Juel1)IMD-4-20141217 |
| Library | Collection | CLSMajor | CLSMinor | Language | Author |
|---|