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@ARTICLE{Alvarez:903551,
author = {Alvarez, Agustin O. and Ravishankar, Sandheep and
Fabregat-Santiago, Francisco},
title = {{C}ombining {M}odulated {T}echniques for the {A}nalysis of
{P}hotosensitive {D}evices},
journal = {Small methods},
volume = {5},
number = {10},
issn = {2366-9608},
address = {Weinheim},
publisher = {WILEY-VCH Verlag GmbH $\&$ Co. KGaA},
reportid = {FZJ-2021-05219},
pages = {2100661 -},
year = {2021},
abstract = {Small perturbation techniques such as impedance
spectroscopy (IS), intensity-modulated photocurrent
spectroscopy (IMPS) and intensity-modulated photovoltage
spectroscopy (IMVS) are useful tools to characterize and
model the optoelectronic properties of photovoltaic and
photoelectrochemical devices. The analysis of the impedance
spectra is generally carried out through the modeling of the
internal processes occurring in the device with an
equivalent circuit. Whereas the analysis of the
intensity-modulated spectroscopies is often focused on the
characteristic response times that are associated with
physical mechanisms such as recombination or transport. In
this work, we propose a procedure to analyze photosensitive
devices by combining these three techniques. This procedure
allows the accurate identification of the common equivalent
circuit and the subsequent application to fitting the three
spectra. As a result, together with the electrical
parameters associated to charge transport, accumulation and
recombination, it is possible to obtain optoelectronic
parameters such as the charge separation efficiency,
external and internal quantum efficiency. Our theoretical
approach is experimentally applied in the characterization
of a silicon photodiode, illustrating the intrinsical
relationship between these techniques. This procedure has a
great potential to contribute to the characterization and
understanding of the operating principles that govern the
response of photoactive devices.},
cin = {IEK-5},
ddc = {620},
cid = {I:(DE-Juel1)IEK-5-20101013},
pnm = {121 - Photovoltaik und Windenergie (POF4-121) / 1215 -
Simulations, Theory, Optics, and Analytics (STOA)
(POF4-121)},
pid = {G:(DE-HGF)POF4-121 / G:(DE-HGF)POF4-1215},
typ = {PUB:(DE-HGF)16},
pubmed = {pmid:34927925},
UT = {WOS:000692464600001},
doi = {10.1002/smtd.202100661},
url = {https://juser.fz-juelich.de/record/903551},
}