% IMPORTANT: The following is UTF-8 encoded.  This means that in the presence
% of non-ASCII characters, it will not work with BibTeX 0.99 or older.
% Instead, you should use an up-to-date BibTeX implementation like “bibtex8” or
% “biber”.

@ARTICLE{Grnebaum:903610,
      author       = {Grünebaum, Mariano and Buchheit, Annika and Lürenbaum,
                      Constantin and Winter, Martin and Wiemhöfer, Hans-Dieter},
      title        = {{A} {S}eries of {P}olyhydric {E}sters {A}s {N}ovel
                      {C}andidates for {B}attery {S}olvents in {L}ithium {M}etal
                      {C}ells: {E}lectrochemical {I}nvestigations and {I}nfluences
                      of {M}oisture and {A}lcohol {R}esidues in {C}ontact with
                      {L}ithium {M}etal},
      journal      = {Meeting abstracts},
      volume       = {},
      issn         = {1091-8213},
      address      = {Pennington, NJ},
      publisher    = {Soc.},
      reportid     = {FZJ-2021-05264},
      pages        = {MA2019-04 158},
      year         = {2019},
      abstract     = {In recent years, the lithium metal anode has aroused great
                      interest, not at least through the development of the
                      lithium//sulfur and the lithium//air battery technologies,
                      in all-solid-state batteries. However, the application of
                      lithium metal anodes is limited by safety issues and several
                      failure mechanisms, including, dendrite growth and direct
                      chemical reactions with electrolyte components like battery
                      solvents, which leads to fast capacity losses.In this
                      context, a new series of polyhydric propyl-based esters were
                      investigated, namely n-propyl acetate, isopropyl acetate
                      (monohydric esters), trimethylene diacetate, 1,2-propylene
                      glycol diacetate (dihydric esters) and triacetin (trihydric
                      ester) as attractive and environmental friendly candidates
                      for electrolyte solvents in lithium metal battery
                      applications.The above mentioned organic esters were
                      examined in respect to their reactivity in contact with
                      lithium metal, influenced by water or alcohol impurities.
                      The resulting reaction products were analyzed and determined
                      via 1H-NMR spectroscopy. Additional experiments were
                      performed and the resulting products compared to anticipated
                      reaction products which were prepared separately, to
                      evidence possible reaction mechanisms like the occurrence of
                      a CLAISEN-condensation.Furthermore, the here mentioned
                      propyl-based esters and the reaction products were analyzed
                      by cyclic voltammetry against copper, platinum and aluminum
                      as working electrode to evaluate the anodic and cathodic
                      stability, as well as possible anodic dissolution reactions
                      in the presence of LiTFSI as conducting salt.In both cases,
                      the reactivity in contact with lithium metal and the anodic
                      dissolution of aluminum, a reactivity could be observed
                      whereupon the trihydric esters were least reactive followed
                      by the dihydric and monohydric esters.In absence of water
                      and alcohols all investigated esters show no detectable
                      reaction with lithium metal.},
      cin          = {IEK-12},
      ddc          = {540},
      cid          = {I:(DE-Juel1)IEK-12-20141217},
      pnm          = {1221 - Fundamentals and Materials (POF4-122)},
      pid          = {G:(DE-HGF)POF4-1221},
      typ          = {PUB:(DE-HGF)16},
      doi          = {10.1149/MA2019-04/3/158},
      url          = {https://juser.fz-juelich.de/record/903610},
}