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| 001 | 903683 | ||
| 005 | 20240712112820.0 | ||
| 024 | 7 | _ | |a 10.1002/elsa.202100068 |2 doi |
| 024 | 7 | _ | |a 2128/31704 |2 Handle |
| 024 | 7 | _ | |a WOS:001136690800017 |2 WOS |
| 037 | _ | _ | |a FZJ-2021-05332 |
| 082 | _ | _ | |a 540 |
| 100 | 1 | _ | |a Jovanovic, Sven |0 P:(DE-Juel1)169518 |b 0 |e Corresponding author |u fzj |
| 245 | _ | _ | |a Lithium intercalation into graphite: In operando analysis of Raman signal widths |
| 260 | _ | _ | |a Weinheim |c 2022 |b Wiley-VCH Verlag GmbH & Co KGaA |
| 336 | 7 | _ | |a article |2 DRIVER |
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| 336 | 7 | _ | |a Journal Article |0 0 |2 EndNote |
| 520 | _ | _ | |a The mechanism of reversible lithium intercalation in graphite anodes is still not fully understood. In operando Raman spectroscopy provides a sensitive means to monitor structural changes during the intercalation process. Analysis of the D-band to G-band intensity ratio (D/G ratio) is a common method to study the structure of carbon materials. However, this approach is complicated for the investigation of graphite anodes during battery cycling, as the D-band disappears with the onset of lithium intercalation. To circumvent this issue, the D/G ratio can be replaced by using the G-band full-width-at-half-maximum (FWHM). In this study, an investigation of the G-band FWHM during battery cell cycling is demonstrated as an alternative to monitor the intercalation of lithium into a graphite electrode. It was observed that lithium intercalation already occurs to a small extent during solid–electrolyte interphase (SEI) formation and that the formation of staged intercalation compounds leads to a continuous deformation of the boundary graphene layer. |
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| 700 | 1 | _ | |a Jakes, Peter |0 P:(DE-Juel1)156296 |b 1 |u fzj |
| 700 | 1 | _ | |a Merz, Steffen |0 P:(DE-Juel1)129503 |b 2 |
| 700 | 1 | _ | |a Eichel, Rüdiger-A. |0 P:(DE-Juel1)156123 |b 3 |
| 700 | 1 | _ | |a Granwehr, Josef |0 P:(DE-Juel1)162401 |b 4 |u fzj |
| 773 | _ | _ | |a 10.1002/elsa.202100068 |0 PERI:(DE-600)2984616-X |n 4 |p e2100068 |t Electrochemical science advances |v 2 |y 2022 |x 2698-5977 |
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