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@ARTICLE{Nogueira:903717,
author = {Nogueira, André E. and da Silva, Gelson T. S. T. and
Oliveira, Jéssica A. and Torres, Juliana A. and da Silva,
Mitchell G. S. and Carmo, Marcelo and Ribeiro, Caue},
title = {{U}nveiling {C}u{O} role in {CO}2 photoreduction process
– {C}atalyst or reactant?},
journal = {Catalysis communications},
volume = {137},
issn = {1566-7367},
address = {Amsterdam},
publisher = {Elsevier},
reportid = {FZJ-2021-05357},
pages = {105929 -},
year = {2020},
note = {Kein Post print vorhanden},
abstract = {We systematically investigated CO2 photoreduction catalyzed
by CuO from different synthetic methods (solvothermal,
coprecipitation and solid-state reaction) to understand
which mechanism is prevailing for this reaction. The results
showed that CuO acts as a reactant during CO2 reduction
through copper carbonate formation rather than a catalyst,
but the as-formed Cu2(OH)2CO3 (malachite) is active as
catalyst for the same reaction. Significant CO2 conversion
was observed during the CuO carbonation process, reducing to
lower conversion levels after complete conversion to copper
carbonate.},
cin = {IEK-14},
ddc = {540},
cid = {I:(DE-Juel1)IEK-14-20191129},
pnm = {1231 - Electrochemistry for Hydrogen (POF4-123)},
pid = {G:(DE-HGF)POF4-1231},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000519664200003},
doi = {10.1016/j.catcom.2020.105929},
url = {https://juser.fz-juelich.de/record/903717},
}