TY  - JOUR
AU  - Ihrig, Martin
AU  - Ye, Ruijie
AU  - Laptev, Alexander
AU  - Grüner, Daniel
AU  - Guerdelli, Rayan
AU  - Scheld, Walter Sebastian
AU  - Finsterbusch, Martin
AU  - Wiemhöfer, Hans-Dieter
AU  - Fattakhova-Rohlfing, Dina
AU  - Guillon, Olivier
TI  - Polymer–Ceramic Composite Cathode with Enhanced Storage Capacity Manufactured by Field-Assisted Sintering and Infiltration
JO  - ACS applied energy materials
VL  - 4
IS  - 10
SN  - 2574-0962
CY  - Washington, DC
PB  - ACS Publications
M1  - FZJ-2021-05431
SP  - 10428 - 10432
PY  - 2021
AB  - Polymer–ceramic all-solid-state Li batteries (ASSLBs) combine the advantages of fully inorganic and polymer-based ASSLBs. In particular, the application of proposed polymer–ceramic composite cathodes could be essential for the enhancement of the energy storage capacity of ASSLBs. The use of a modified field-assisted sintering technique with adjustable pressure and with alternative mica foil enables the fabrication of porous cathodes at a reduced sintering temperature and without side phase formation. This allows sintering of a porous LiCoO2/Li7La3Zr2O12:Ta composite network suitable for polymer infiltration and assembly in an ASSLB from the cathode side. The ceramic LiCoO2/Li7La3Zr2O12:Ta composite cathodes infiltrated with an ion-conducting polymer have shown an enhanced areal storage capacity.
LB  - PUB:(DE-HGF)16
UR  - <Go to ISI:>//WOS:000711236300002
DO  - DOI:10.1021/acsaem.1c02667
UR  - https://juser.fz-juelich.de/record/903797
ER  -