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@ARTICLE{LohmannRichters:903812,
author = {Lohmann-Richters, F. P. and Renz, S. and Lehnert, W. and
Müller, Martin and Carmo, M.},
title = {{R}eview—{C}hallenges and {O}pportunities for {I}ncreased
{C}urrent {D}ensity in {A}lkaline {E}lectrolysis by
{I}ncreasing the {O}perating {T}emperature},
journal = {Journal of the Electrochemical Society},
volume = {168},
number = {11},
issn = {0013-4651},
address = {Bristol},
publisher = {IOP Publishing},
reportid = {FZJ-2021-05445},
pages = {114501 -},
year = {2021},
abstract = {The highly-efficient, low-cost, large-scale production of
green hydrogen by means of electrolysis is urgently needed
for achieving a decarbonized energy supply. Alkaline water
electrolysis is a wellestablished technology with relatively
low costs which does not require scarce noble metal
catalysts, but it suffers from low current densities.
Increasing the operating temperature can allow this
limitation to be overcome. This article summarizes both
long-standing and recent developments in alkaline water
electrolysis at increased temperature and sheds light on the
challenges and unique opportunities of this approach. It is
found that electrochemical improvements induced by higher
temperature enable competitive current densities and offer
unique possibilities for thermal management. The selection
and development of stable materials, catalysts, and
diaphragms is challenging, but some have proven long-term
stability up to at least 150 °C and promising candidates
are available at up to 200 °C. Further research will allow
the present challenges to be overcome by understanding and
improving the basic processes and components for alkaline
electrolysis at increased temperature and capitalizing on
its unique advantages.},
cin = {IEK-14},
ddc = {660},
cid = {I:(DE-Juel1)IEK-14-20191129},
pnm = {1231 - Electrochemistry for Hydrogen (POF4-123)},
pid = {G:(DE-HGF)POF4-1231},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000717274400001},
doi = {10.1149/1945-7111/ac34cc},
url = {https://juser.fz-juelich.de/record/903812},
}