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@ARTICLE{Carbajo:903987,
      author       = {Carbajo, J. and Quintanilla, A. and Garcia-Costa, A. L. and
                      González-Julián, J. and Belmonte, M. and Miranzo, P. and
                      Osendi, M. I. and Casas, J. A.},
      title        = {{T}he influence of the catalyst on the {CO} formation
                      during catalytic wet peroxide oxidation process},
      journal      = {Catalysis today},
      volume       = {361},
      issn         = {0920-5861},
      address      = {Amsterdam},
      publisher    = {Elsevier},
      reportid     = {FZJ-2021-05557},
      pages        = {30 - 36},
      year         = {2021},
      abstract     = {Herein, the formation of carbon monoxide as a harmful
                      product upon the Catalytic Wet Peroxide Oxidation process is
                      studied in presence of different solid catalysts: an iron
                      supported activated carbon catalyst, a metal-free catalyst
                      based on Graphene Nanoplatelets, and $1.6 wt.\%$ Fe
                      containing Cr2AlC MAX phase catalyst. The CWPO performance
                      and the evolution of the gas effluent have been compared to
                      that obtained in a conventional Fenton process.Carbon
                      monoxide yield released was significantly lower in Catalytic
                      Wet Peroxide Oxidation process in relation to that obtained
                      in the Fenton process, where CO concentration reaches a
                      maximum of 6651 mg/Nm3. By contrast, in presence of
                      activated carbon-Fe catalyst and, notably, Graphene
                      Nanoplatelets and Cr2AlC MAX phase catalysts, a more
                      progressive phenol and aromatics intermediates oxidation
                      resulted in a much lower CO maximum concentration in the gas
                      phase at the exit of the reactor of 2454 mg/Nm3,
                      170 mg/Nm3 and 187 mg/Nm3, respectively.Hence, when
                      compared to the homogeneous Fenton oxidation, Catalytic Wet
                      Peroxide Oxidation process results be a more sustainable
                      treatment for high-loaded phenolic wastewaters by decreasing
                      the hazardous CO gaseous emissions avoiding this way a
                      secondary pollution during the oxidation process.},
      cin          = {IEK-1},
      ddc          = {540},
      cid          = {I:(DE-Juel1)IEK-1-20101013},
      pnm          = {899 - ohne Topic (POF4-899)},
      pid          = {G:(DE-HGF)POF4-899},
      typ          = {PUB:(DE-HGF)16},
      UT           = {WOS:000598224600006},
      doi          = {10.1016/j.cattod.2019.12.020},
      url          = {https://juser.fz-juelich.de/record/903987},
}