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| Hauptseite > Publikationsdatenbank > The influence of the catalyst on the CO formation during catalytic wet peroxide oxidation process > print |
| Hauptseite > Publikationsdatenbank > The influence of the catalyst on the CO formation during catalytic wet peroxide oxidation process > print |
| 001 | 903987 | ||
| 005 | 20240711085652.0 | ||
| 024 | 7 | _ | |a 10.1016/j.cattod.2019.12.020 |2 doi |
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| 100 | 1 | _ | |a Carbajo, J. |0 0000-0002-2812-5783 |b 0 |e Corresponding author |
| 245 | _ | _ | |a The influence of the catalyst on the CO formation during catalytic wet peroxide oxidation process |
| 260 | _ | _ | |a Amsterdam |c 2021 |b Elsevier |
| 336 | 7 | _ | |a article |2 DRIVER |
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| 520 | _ | _ | |a Herein, the formation of carbon monoxide as a harmful product upon the Catalytic Wet Peroxide Oxidation process is studied in presence of different solid catalysts: an iron supported activated carbon catalyst, a metal-free catalyst based on Graphene Nanoplatelets, and 1.6 wt.% Fe containing Cr2AlC MAX phase catalyst. The CWPO performance and the evolution of the gas effluent have been compared to that obtained in a conventional Fenton process.Carbon monoxide yield released was significantly lower in Catalytic Wet Peroxide Oxidation process in relation to that obtained in the Fenton process, where CO concentration reaches a maximum of 6651 mg/Nm3. By contrast, in presence of activated carbon-Fe catalyst and, notably, Graphene Nanoplatelets and Cr2AlC MAX phase catalysts, a more progressive phenol and aromatics intermediates oxidation resulted in a much lower CO maximum concentration in the gas phase at the exit of the reactor of 2454 mg/Nm3, 170 mg/Nm3 and 187 mg/Nm3, respectively.Hence, when compared to the homogeneous Fenton oxidation, Catalytic Wet Peroxide Oxidation process results be a more sustainable treatment for high-loaded phenolic wastewaters by decreasing the hazardous CO gaseous emissions avoiding this way a secondary pollution during the oxidation process. |
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| 700 | 1 | _ | |a Quintanilla, A. |0 0000-0002-7255-2547 |b 1 |
| 700 | 1 | _ | |a Garcia-Costa, A. L. |0 0000-0001-5956-3148 |b 2 |
| 700 | 1 | _ | |a González-Julián, J. |0 P:(DE-Juel1)162271 |b 3 |
| 700 | 1 | _ | |a Belmonte, M. |0 0000-0001-6668-6920 |b 4 |
| 700 | 1 | _ | |a Miranzo, P. |0 P:(DE-HGF)0 |b 5 |
| 700 | 1 | _ | |a Osendi, M. I. |0 P:(DE-HGF)0 |b 6 |
| 700 | 1 | _ | |a Casas, J. A. |0 P:(DE-HGF)0 |b 7 |
| 773 | _ | _ | |a 10.1016/j.cattod.2019.12.020 |g Vol. 361, p. 30 - 36 |0 PERI:(DE-600)2012626-8 |p 30 - 36 |t Catalysis today |v 361 |y 2021 |x 0920-5861 |
| 856 | 4 | _ | |u https://juser.fz-juelich.de/record/903987/files/The%20influence%20of%20the%20catalyst%20on%20the%20CO%20formation%20during%20catalytic%20wet%20peroxide%20oxidation%20process.pdf |y OpenAccess |
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