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000903992 1001_ $$0P:(DE-HGF)0$$aLi, Zhenwei$$b0
000903992 245__ $$aMultifunctional cation-vacancy-rich ZnCo2O4 polysulfide-blocking layer for ultrahigh-loading Li-S battery
000903992 260__ $$aAmsterdam [u.a.]$$bElsevier$$c2021
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000903992 520__ $$aThe major hurdle in Li-S battery commercialization is the severe shuttle effect and sluggish reaction kinetics of polysulfide conversion during charge-discharge cycling. Herein, to overcome these barriers, we designed and synthesized Zn defective Zn/Co oxide (ZDZCO) nanosheets, a cation-vacancy-rich bimetallic oxide for the construction of a multifunctional polysulfide-blocking layer. Both theoretical and experimental studies have comprehensively demonstrated that the ZDZCO shows robust binding capability towards polysulfides and a high catalytic ability for fast polysulfide conversion. Through a facile coating process, the multifunctional ZDZCO polysulfide-blocking layer is incorporated on a commercial polypropylene separator, forming a composite separator. The resultant separator facilitates an ultrahigh sulfur loading of 21.06 mg cm-2 and an areal capacity as high as 24.25 mAh cm-2. This study illuminates a promising and practical strategy to construct high-performance Li-S batteries with high sulfur loading.
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000903992 7001_ $$0P:(DE-HGF)0$$aZhang, Qian$$b1
000903992 7001_ $$0P:(DE-HGF)0$$aHencz, Luke$$b2
000903992 7001_ $$0P:(DE-Juel1)145655$$aLiu, Jie$$b3$$eCorresponding author
000903992 7001_ $$0P:(DE-Juel1)174502$$aKaghazchi, Payam$$b4$$ufzj
000903992 7001_ $$0P:(DE-HGF)0$$aHan, Jishu$$b5
000903992 7001_ $$0P:(DE-Juel1)184889$$aWang, Lei$$b6$$eCorresponding author
000903992 7001_ $$0P:(DE-HGF)0$$aZhang, Shanqing$$b7$$eCorresponding author
000903992 773__ $$0PERI:(DE-600)2648700-7$$a10.1016/j.nanoen.2021.106331$$gVol. 89, p. 106331 -$$p106331 -$$tNano energy$$v89$$x2211-2855$$y2021
000903992 8564_ $$uhttps://juser.fz-juelich.de/record/903992/files/Multifunctional-cation-vacancy.pdf$$yPublished on 2021-07-10. Available in OpenAccess from 2023-07-10.
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