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@ARTICLE{Liu:903993,
author = {Liu, Xianyu and Ma, Liwen and Du, Yehong and Lu, Qiongqiong
and Yang, Aikai and Wang, Xinyu},
title = {{V}anadium {P}entoxide {N}anofibers/{C}arbon {N}anotubes
{H}ybrid {F}ilm for {H}igh-{P}erformance {A}queous
{Z}inc-{I}on {B}atteries},
journal = {Nanomaterials},
volume = {11},
number = {4},
issn = {2079-4991},
address = {Basel},
publisher = {MDPI},
reportid = {FZJ-2021-05563},
pages = {1054 -},
year = {2021},
abstract = {Aqueous zinc-ion batteries (ZIBs) with the characteristics
of low production costs and good safety have been regarded
as ideal candidates for large-scale energy storage
applications. However, the nonconductive and non-redox
active polymer used as the binder in the traditional
preparation of electrodes hinders the exposure of active
sites and limits the diffusion of ions, compromising the
energy density of the electrode in ZIBs. Herein, we
fabricated vanadium pentoxide nanofibers/carbon nanotubes
(V2O5/CNTs) hybrid films as binder-free cathodes for ZIBs.
High ionic conductivity and electronic conductivity were
enabled in the V2O5/CNTs film due to the porous structure of
the film and the introduction of carbon nanotubes with high
electronic conductivity. As a result, the batteries based on
the V2O5/CNTs film exhibited a higher capacity of 390 mAh
g−1 at 1 A g−1, as compared to batteries based on V2O5
(263 mAh g−1). Even at 5 A g−1, the battery based on the
V2O5/CNTs film maintained a capacity of 250 mAh g−1 after
2000 cycles with a capacity retention of $94\%.$ In
addition, the V2O5/CNTs film electrode also showed a high
energy/power density (e.g., 67 kW kg−1/267 Wh kg−1). The
capacitance response and rapid diffusion coefficient of Zn2+
(~10−8 cm−2 s−1) can explain the excellent rate
capability of V2O5/CNTs. The vanadium pentoxide
nanofibers/carbon nanotubes hybrid film as binder-free
cathodes showed a high capability and a stable cyclability,
demonstrating that it is highly promising for large-scale
energy storage applications},
cin = {IEK-1},
ddc = {540},
cid = {I:(DE-Juel1)IEK-1-20101013},
pnm = {1221 - Fundamentals and Materials (POF4-122)},
pid = {G:(DE-HGF)POF4-1221},
typ = {PUB:(DE-HGF)16},
pubmed = {33924150},
UT = {WOS:000643354400001},
doi = {10.3390/nano11041054},
url = {https://juser.fz-juelich.de/record/903993},
}