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@ARTICLE{Liu:903994,
      author       = {Liu, Zenghua and Ren, Junfeng and Wang, Fanghui and Liu,
                      Xiaobin and Zhang, Qian and Liu, Jie and Kaghazchi, Payam
                      and Ma, Dingxuan and Chi, Zhenzhen and Wang, Lei},
      title        = {{T}uning {S}urface {E}nergy of {Z}n {A}nodes via {S}n
                      {H}eteroatom {D}oping {E}nabled by a {C}odeposition for
                      {U}ltralong {L}ife {S}pan {D}endrite-{F}ree {A}queous
                      {Z}n-{I}on {B}atteries},
      journal      = {ACS applied materials $\&$ interfaces},
      volume       = {13},
      number       = {23},
      issn         = {1944-8244},
      address      = {Washington, DC},
      publisher    = {Soc.},
      reportid     = {FZJ-2021-05564},
      pages        = {27085 - 27095},
      year         = {2021},
      abstract     = {Aqueous Zn-ion batteries (AZBs) have been considered as one
                      of the most promising large-scale energy storage systems,
                      owing to the advantages of raw material abundance, low cost,
                      and eco-friendliness. However, the severe growth of Zn
                      dendrites leads to poor stability and low Coulombic
                      efficiency of AZBs. Herein, to effectively inhibit the
                      growth of Zn dendrites, a new strategy has been proposed,
                      i.e., tuning the surface energy of the Zn anode. This
                      strategy can be achieved by in situ doping of Sn heteroatoms
                      in the lattice of metallic Zn via codeposition of Sn and Zn
                      with a small amount of the SnCl2 electrolyte additive.
                      Density functional theory calculations have suggested that
                      Sn heteroatom doping can sharply decrease the surface free
                      energy of the Zn anode. As a consequence, driven by the
                      locally strong electric field, metallic Sn tends to deposit
                      at the tips of the Zn anode, thus decreases the surface
                      energy and growth of Zn at the tips, resulting in a
                      dendrite-free Zn anode. The positive effect of the SnCl2
                      additive has been demonstrated in both the Zn∥Zn symmetric
                      battery and the Zn/LFP and Zn/HATN full cell. This novel
                      strategy can light a new way to suppress Zn dendrites for
                      long life span Zn-ion batteries.},
      cin          = {IEK-1},
      ddc          = {600},
      cid          = {I:(DE-Juel1)IEK-1-20101013},
      pnm          = {1221 - Fundamentals and Materials (POF4-122)},
      pid          = {G:(DE-HGF)POF4-1221},
      typ          = {PUB:(DE-HGF)16},
      pubmed       = {34080420},
      UT           = {WOS:000664289800041},
      doi          = {10.1021/acsami.1c06002},
      url          = {https://juser.fz-juelich.de/record/903994},
}