%0 Journal Article
%A Nimax, Patrick R.
%A Rotthowe, Nils
%A Zoller, Florian
%A Blockhaus, Tobias
%A Wagner, Fritz
%A Fattakhova, Dina
%A Sünkel, Karlheinz
%T Coordination polymers of 5-substituted 1,2,3,4-tetracyanocyclopentadienides: structural and electrochemical properties of complex compounds of 5-amino- and 5-nitro-tetracyanocyclopentadienide
%J Dalton transactions
%V 50
%N 47
%@ 0300-9246
%C London
%I Soc.
%M FZJ-2021-05565
%P 17643 - 17652
%D 2021
%X Compounds of the 5 amino (ATCC) and 5 nitro 1,2,3,4 tetracyanocyclopentadienide (NTCC) ligand with iron(II) and iron(III), silver(I) and potassium(I) were prepared and characterized by electrochemical methods using EPR, cyclic voltammetry and Mößbauer spectroscopy as well as UV-Vis spectroscopy. The investigation sheds light on the free radical activity in non- as well as transition metal compounds, and shows signs of photoinduced electron transfer in transition metal compounds of the ligands. We characterized silver(I) and potassium compounds of the compounds via X-ray diffraction, with one of the structures exhibiting a porous coordination polymer.
%F PUB:(DE-HGF)16
%9 Journal Article
%$ pmid:34806109
%U <Go to ISI:>//WOS:000720965400001
%R 10.1039/D1DT02866A
%U https://juser.fz-juelich.de/record/903995