TY  - JOUR
AU  - Nimax, Patrick R.
AU  - Rotthowe, Nils
AU  - Zoller, Florian
AU  - Blockhaus, Tobias
AU  - Wagner, Fritz
AU  - Fattakhova, Dina
AU  - Sünkel, Karlheinz
TI  - Coordination polymers of 5-substituted 1,2,3,4-tetracyanocyclopentadienides: structural and electrochemical properties of complex compounds of 5-amino- and 5-nitro-tetracyanocyclopentadienide
JO  - Dalton transactions
VL  - 50
IS  - 47
SN  - 0300-9246
CY  - London
PB  - Soc.
M1  - FZJ-2021-05565
SP  - 17643 - 17652
PY  - 2021
AB  - Compounds of the 5 amino (ATCC) and 5 nitro 1,2,3,4 tetracyanocyclopentadienide (NTCC) ligand with iron(II) and iron(III), silver(I) and potassium(I) were prepared and characterized by electrochemical methods using EPR, cyclic voltammetry and Mößbauer spectroscopy as well as UV-Vis spectroscopy. The investigation sheds light on the free radical activity in non- as well as transition metal compounds, and shows signs of photoinduced electron transfer in transition metal compounds of the ligands. We characterized silver(I) and potassium compounds of the compounds via X-ray diffraction, with one of the structures exhibiting a porous coordination polymer.
LB  - PUB:(DE-HGF)16
C6  - pmid:34806109
UR  - <Go to ISI:>//WOS:000720965400001
DO  - DOI:10.1039/D1DT02866A
UR  - https://juser.fz-juelich.de/record/903995
ER  -