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@ARTICLE{Sun:904010,
author = {Sun, Ying and Wang, Xingchao and Yang, Aikai and Huang,
Yudai and Jia, Wei and Jia, Dianzeng and Cheng, Fangyi and
Xu, Mengjiao and Li, Maohua and Lu, Yi},
title = {{F}unctional separator with a lightweight carbon-coating
for stable, high-capacity organic lithium batteries},
journal = {The chemical engineering journal},
volume = {418},
issn = {1385-8947},
address = {Amsterdam},
publisher = {Elsevier},
reportid = {FZJ-2021-05580},
pages = {129404 -},
year = {2021},
note = {Kein Post-print vorhanden},
abstract = {A major challenge facing organic rechargeable batteries is
the problem of the dissolution and shuttle effect of organic
cathodes in aprotic electrolytes, resulting in limited
capacity, low cyclability and poor rate performance. Herein,
a functional polypropylene separator coated with Ketjen
black (C@PP) was introduced to tackle the shuttle issue. The
inhibitory effect on quinone shuttle correlates with
physical barrier and excellent adsorption of Ketjen black
(KB), as proved by a series of spectroscopy studies. With
the C@PP separator, quinone cathodes including
pentacene-5,7,12,14-tetrone (PT), Calix[4] quinone (C4Q),
9,10-anthraquinone (AQ) and 9,10-phenanthrenequinone (PQ)
demonstrated high reversible capacity and excellent cyclic
stability in Li storage. Specially, PT exhibited high
capacity (>300 mAh g−1), long-term cyclability $(~0.06\%$
decay per cycle over 400 cycles at 0.5 C) and fast kinetic
(5 C). C4Q delivered high energy density (782 Wh kg−1) and
respectable cyclability $(~60\%$ after 500 cycles). This
facile and versatile separator modifying strategy opens a
new avenue for solving quinone electrode issues to achieve
high-performance OLBs.},
cin = {IEK-1},
cid = {I:(DE-Juel1)IEK-1-20101013},
pnm = {899 - ohne Topic (POF4-899)},
pid = {G:(DE-HGF)POF4-899},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000656154100007},
doi = {10.1016/j.cej.2021.129404},
url = {https://juser.fz-juelich.de/record/904010},
}