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@ARTICLE{Eliwi:904099,
author = {Eliwi, Abed Alrhman and Malekshahi Byranvand, Mahdi and
Fassl, Paul and Khan, Motiur Rahman and Hossain, Ihteaz
Muhaimeen and Frericks, Markus and Ternes, Simon and
Abzieher, Tobias and Schwenzer, Jonas A. and Mayer, Thomas
and Hofmann, Jan P. and Richards, Bryce S. and Lemmer, Uli
and Saliba, Michael and Paetzold, Ulrich W.},
title = {{O}ptimization of {S}n{O}2 electron transport layer for
efficient planar perovskite solar cells with very low
hysteresis},
journal = {Materials advances},
volume = {3},
number = {1},
issn = {2633-5409},
address = {Cambridge},
publisher = {Royal Society of Chemistry},
reportid = {FZJ-2021-05669},
pages = {456-466},
year = {2022},
abstract = {Nanostructured tin oxide (SnO2) is a very promising
electron transport layer (ETL) for perovskite solar cells
(PSCs) that allows low-temperature processing in the planar
n–i–p architecture. However, minimizing
current–voltage (J–V) hysteresis and optimizing charge
extraction for PSCs in this architecture remains a
challenge. In response to this, we study and optimize
different types of single- and bilayer SnO2 ETLs. Detailed
characterization of the optoelectronic properties reveals
that a bilayer ETL composed of lithium (Li)-doped compact
SnO2 (c(Li)-SnO2) at the bottom and potassium-capped SnO2
nanoparticle layers (NP-SnO2) at the top enhances the
electron extraction and charge transport properties of PSCs
and reduces the degree of ion migration. This results in an
improved PCE and a strongly reduced J–V hysteresis for
PSCs with a bilayer c(Li)-NP-SnO2 ETL as compared to
reference PSCs with a single-layer or undoped bilayer ETL.
The champion PSC with c(Li)-NP-SnO2 ETL shows a high
stabilized PCE of up to $18.5\%$ compared to $15.7\%,$
$12.5\%$ and $16.3\%$ for PSCs with c-SnO2, c(Li)-SnO2 and
c-NP-SnO2 as ETL, respectively.},
cin = {IEK-5},
ddc = {540},
cid = {I:(DE-Juel1)IEK-5-20101013},
pnm = {1213 - Cell Design and Development (POF4-121)},
pid = {G:(DE-HGF)POF4-1213},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000717741700001},
doi = {10.1039/D1MA00585E},
url = {https://juser.fz-juelich.de/record/904099},
}