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@ARTICLE{Li:904104,
author = {Li, Feng and Duan, Weiyuan and Pomaska, Manuel and Köhler,
Malte and Ding, Kaining and Pu, Yong and Aeberhard, Urs and
Rau, Uwe},
title = {{Q}uantum {T}ransport across {A}morphous-{C}rystalline
{I}nterfaces in {T}unnel {O}xide {P}assivated {C}ontact
{S}olar {C}ells: {D}irect versus {D}efect-{A}ssisted
{T}unneling},
journal = {Chinese physics letters},
volume = {38},
number = {3},
issn = {0256-307X},
address = {Bristol},
publisher = {IOP Publ.},
reportid = {FZJ-2021-05674},
pages = {036301 -},
year = {2021},
abstract = {Tunnel oxide passivated contact solar cells have evolved
into one of the most promising silicon solar cell concepts
of the past decade, achieving a record efficiency of $25\%.$
We study the transport mechanisms of realistic tunnel oxide
structures, as encountered in tunnel oxide passivating
contact (TOPCon) solar cells. Tunneling transport is
affected by various factors, including oxide layer
thickness, hydrogen passivation, and oxygen vacancies. When
the thickness of the tunnel oxide layer increases, a faster
decline of conductivity is obtained computationally than
that observed experimentally. Direct tunneling seems not to
explain the transport characteristics of tunnel oxide
contacts. Indeed, it can be shown that recombination of
multiple oxygen defects in a-SiOx can generate atomic
silicon nanowires in the tunnel layer. Accordingly, new and
energetically favorable transmission channels are generated,
which dramatically increase the total current, and could
provide an explanation for our experimental results. Our
work proves that hydrogenated silicon oxide (SiOx:H)
facilitates high-quality passivation, and features good
electrical conductivity, making it a promising hydrogenation
material for TOPCon solar cells. By carefully selecting the
experimental conditions for tuning the SiOx:H layer, we
anticipate the simultaneous achievement of high open-circuit
voltage and low contact resistance.},
cin = {IEK-5},
ddc = {530},
cid = {I:(DE-Juel1)IEK-5-20101013},
pnm = {1215 - Simulations, Theory, Optics, and Analytics (STOA)
(POF4-121)},
pid = {G:(DE-HGF)POF4-1215},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000632840900001},
doi = {10.1088/0256-307X/38/3/036301},
url = {https://juser.fz-juelich.de/record/904104},
}