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@ARTICLE{Mohammadi:904107,
author = {Mohammadi, Mahdi and Gholipour, Somayeh and Malekshahi
Byranvand, Mahdi and Abdi, Yaser and Taghavinia, Nima and
Saliba, Michael},
title = {{E}ncapsulation {S}trategies for {H}ighly {S}table
{P}erovskite {S}olar {C}ells under {S}evere {S}tress
{T}esting: {D}amp {H}eat, {F}reezing, and {O}utdoor
{I}llumination {C}onditions},
journal = {ACS applied materials $\&$ interfaces},
volume = {13},
number = {38},
issn = {1944-8244},
address = {Washington, DC},
publisher = {Soc.},
reportid = {FZJ-2021-05677},
pages = {45455 - 45464},
year = {2021},
abstract = {A key direction toward managing extrinsic instabilities in
perovskite solar cells (PSCs) is encapsulation. Thus, a
suitable sealing layer is required for an efficient device
encapsulation, preventing moisture and oxygen ingression
into the perovskite layer. In this work, a solution-based,
low-cost, and commercially available bilayer structure of
poly(methyl methacrylate)/styrene-butadiene (PMMA/SB) is
investigated for PSCs encapsulation. Encapsulated devices
retained $80\%$ of the initial power conversion efficiency
(PCE) at 85 °C temperature and $85\%$ relative humidity
after 100 h, while reference devices without SB (only PMMA)
suffer from rapid and intense degradation after only 2 h,
under the same condition. In addition, encapsulated devices
retained $95\%$ of the initial PCE under −15 °C freezing
temperature after 6 h and retained $∼80\%$ of the initial
PCE after immersion in HCl $(37\%)$ for 90 min. Moreover,
applying an additional aluminum metal sheet on the PMMA/SB
protective bilayer leads to the improvement of device
stability up to 500 h under outdoor illumination, retaining
almost $90\%$ of the initial PCE. Considering the urge to
develop reliable, scalable, and simple encapsulation for
future large-area PSCs, this work establishes solution-based
bilayer encapsulation, which is applicable for flexible
solar modules as well as other optoelectronic devices such
as light-emitting devices and photodetectors.},
cin = {IEK-5},
ddc = {600},
cid = {I:(DE-Juel1)IEK-5-20101013},
pnm = {1214 - Modules, stability, performance and specific
applications (POF4-121)},
pid = {G:(DE-HGF)POF4-1214},
typ = {PUB:(DE-HGF)16},
pubmed = {34528780},
UT = {WOS:000703995900032},
doi = {10.1021/acsami.1c11628},
url = {https://juser.fz-juelich.de/record/904107},
}