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@ARTICLE{Kretzschmar:904173,
author = {Kretzschmar, Ansgar and Selmert, Victor and Weinrich,
Henning and Kungl, Hans and Tempel, Hermann and Eichel,
Rüdiger-A.},
title = {{S}tudy of {CO} 2 {S}orption {K}inetics on {E}lectrospun
{P}olyacrylonitrile‐{B}ased {C}arbon {N}anofibers},
journal = {Chemical engineering $\&$ technology},
volume = {44},
number = {7},
issn = {0930-7516},
address = {Weinheim},
publisher = {Wiley-VCH Verl.-Ges.},
reportid = {FZJ-2021-05743},
pages = {1168 - 1177},
year = {2021},
abstract = {Electrospun carbon nanofibers (CNFs) exhibit a decent CO2
sorption capacity and outstanding CO2/N2 selectivity. In
this work, the sorption rate as another practically relevant
parameter for CO2 adsorption is analyzed for different
carbonization temperatures. Equilibration curves obtained
from different CO2 sorption isotherms are discussed
qualitatively and quantitatively, employing empirical models
for pseudo-first- and second-order reactions. The sorption
rate constants are found to be highly dependent on the
carbonization temperature of the CNFs and the applied
pressure during the measurement. Furthermore, two distinct
processes of sorption are observed, which are attributed to
different sorption sites on the surface and the inner volume
of the CNFs.},
cin = {IEK-9},
ddc = {660},
cid = {I:(DE-Juel1)IEK-9-20110218},
pnm = {1223 - Batteries in Application (POF4-122)},
pid = {G:(DE-HGF)POF4-1223},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000647231200001},
doi = {10.1002/ceat.202000463},
url = {https://juser.fz-juelich.de/record/904173},
}