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@ARTICLE{Liu:904175,
author = {Liu, Xiangsi and Liang, Ziteng and Xiang, Yuxuan and Lin,
Min and Li, Qi and Liu, Zigeng and Zhong, Guiming and Fu,
Riqiang and Yang, Yong},
title = {{S}olid‐{S}tate {NMR} and {MRI} {S}pectroscopy for
{L}i/{N}a {B}atteries: {M}aterials, {I}nterface, and {I}n
{S}itu {C}haracterization},
journal = {Advanced materials},
volume = {33},
number = {50},
issn = {0935-9648},
address = {Weinheim},
publisher = {Wiley-VCH},
reportid = {FZJ-2021-05745},
pages = {2005878 -},
year = {2021},
abstract = {Enhancing the electrochemical performance of batteries,
including the lifespan, energy, and power densities, is an
everlasting quest for the rechargeable battery community.
However, the dynamic and coupled (electro)chemical processes
that occur in the electrode materials as well as at the
electrode/electrolyte interfaces complicate the
investigation of their working and decay mechanisms. Herein,
the recent developments and applications of solid-state
nuclear magnetic resonance (ssNMR) and magnetic resonance
imaging (MRI) techniques in Li/Na batteries are reviewed.
Several typical cases including the applications of NMR
spectroscopy for the investigation of the pristine structure
and the dynamic structural evolution of materials are first
emphasized. The NMR applications in analyzing the solid
electrolyte interfaces (SEI) on the electrode are further
concluded, involving the identification of SEI components
and investigation of ionic motion through the interfaces.
Beyond, the new development of in situ NMR and MRI
techniques are highlighted, including their advantages,
challenges, applications and the design principle of in situ
cell. In the end, a prospect about how to use ssNMR in
battery research from the perspectives of materials,
interface, and in situ NMR, aiming at obtaining deeper
insight of batteries with the assistance of ssNMR is
represented.},
cin = {IEK-9},
ddc = {660},
cid = {I:(DE-Juel1)IEK-9-20110218},
pnm = {1232 - Power-based Fuels and Chemicals (POF4-123)},
pid = {G:(DE-HGF)POF4-1232},
typ = {PUB:(DE-HGF)16},
pubmed = {33788341},
UT = {WOS:000635235300001},
doi = {10.1002/adma.202005878},
url = {https://juser.fz-juelich.de/record/904175},
}