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000904180 1001_ $$0P:(DE-HGF)0$$aTürk, Hanna$$b0
000904180 245__ $$aComplexions at the Electrolyte/Electrode Interface in Solid Oxide Cells
000904180 260__ $$aWeinheim$$bWiley-VCH$$c2021
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000904180 520__ $$aRapid deactivation presently limits a wide spread use of high-temperature solid oxide cells (SOCs) as otherwise highly efficient chemical energy converters. With deactivation triggered by the ongoing conversion reactions, an atomic-scale understanding of the active triple-phase boundary between electrolyte, electrode, and gas phase is essential to increase cell performance. Here, a multi-method approach is used comprising transmission electron microscopy and first-principles calculations and molecular simulations to untangle the atomic arrangement of the prototypical SOC interface between a lanthanum strontium manganite (LSM) anode and a yttria-stabilized zirconia (YSZ) electrolyte in the as-prepared state after sintering. An interlayer of self-limited width with partial amorphization and strong compositional gradient is identified, thus exhibiting the characteristics of a complexion that is stabilized by the confinement between two bulk phases. This offers a new perspective to understand the function of SOCs at the atomic scale. Moreover, it opens up a hitherto unrealized design space to tune the conversion efficiency.
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000904180 7001_ $$0P:(DE-HGF)0$$aSchmidt, Franz-Philipp$$b1
000904180 7001_ $$0P:(DE-HGF)0$$aGötsch, Thomas$$b2$$eCorresponding author
000904180 7001_ $$0P:(DE-HGF)0$$aGirgsdies, Frank$$b3
000904180 7001_ $$0P:(DE-HGF)0$$aHammud, Adnan$$b4
000904180 7001_ $$0P:(DE-HGF)0$$aIvanov, Danail$$b5
000904180 7001_ $$0P:(DE-Juel1)129936$$aVinke, Izaak C.$$b6
000904180 7001_ $$0P:(DE-Juel1)129952$$ade Haart, L. G. J.$$b7
000904180 7001_ $$0P:(DE-Juel1)156123$$aEichel, Rüdiger-A.$$b8
000904180 7001_ $$0P:(DE-HGF)0$$aReuter, Karsten$$b9
000904180 7001_ $$0P:(DE-HGF)0$$aSchlögl, Robert$$b10
000904180 7001_ $$0P:(DE-HGF)0$$aKnop-Gericke, Axel$$b11
000904180 7001_ $$0P:(DE-Juel1)184961$$aScheurer, Christoph$$b12
000904180 7001_ $$0P:(DE-HGF)0$$aLunkenbein, Thomas$$b13
000904180 773__ $$0PERI:(DE-600)2750376-8$$a10.1002/admi.202100967$$gVol. 8, no. 18, p. 2100967 -$$n18$$p2100967 -$$tAdvanced materials interfaces$$v8$$x2196-7350$$y2021
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