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@ARTICLE{Wang:904365,
      author       = {Wang, Chunli and Zhang, Zhihao and Fu, Xiaoheng and Zhang,
                      Jing and Dhont, Jan K. G.},
      title        = {{F}ormation of amorphous {P}b{C}r{O} 4 nanoparticles
                      depending on the quantitative control of interfacial water},
      journal      = {Molecular systems design $\&$ engineering},
      volume       = {6},
      number       = {11},
      issn         = {2058-9689},
      address      = {Cambridge},
      publisher    = {Royal Society of Chemistry},
      reportid     = {FZJ-2021-05935},
      pages        = {918 - 924},
      year         = {2021},
      abstract     = {Interfacial water confined in the microemulsions shows
                      behaviors different to normal bulk water and could affect
                      the reactions involved at the interface. In this work, the
                      content of interfacial and bulk water in the parental
                      microemulsions for the reactions was first quantitatively
                      determined by Fourier-transform infrared (FTIR)
                      spectroscopy. The nucleation and growth of PbCrO4
                      nanoparticles in the microemulsions were studied on the
                      basis of the FTIR results. By controlling the water ratio in
                      micellar droplets, amorphous nanoparticles were obtained in
                      the interfacial water, while nanocrystals were produced in
                      the bulk water. The amorphous nanoparticles with defined
                      shapes are quite stable in the microemulsion solution and
                      show no transformation to crystallites for several days.
                      This work offers a delicate way to control the metastable
                      amorphous precursor for follow-up crystallization.},
      cin          = {IBI-4},
      ddc          = {570},
      cid          = {I:(DE-Juel1)IBI-4-20200312},
      pnm          = {5241 - Molecular Information Processing in Cellular Systems
                      (POF4-524)},
      pid          = {G:(DE-HGF)POF4-5241},
      typ          = {PUB:(DE-HGF)16},
      UT           = {WOS:000683363300001},
      doi          = {10.1039/D1ME00071C},
      url          = {https://juser.fz-juelich.de/record/904365},
}