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@ARTICLE{Feygenson:904366,
author = {Feygenson, M. and Novoselov, D. Y. and Mazannikova, M. A.
and Korotin, D. M. and Bushinsky, M. and Karpinsky, D. and
Hanfland, M. and Sazonov, A. and Savvin, S. and Porcher, F.
and Svetogorov, R. and Veligzhanin, A. and Tiutiunnikov, S.
and Arumugam, S. and Sikolenko, V.},
title = {{P}ressure-induced structural and magnetic phase
transitions in {L}a 0.75 {B}a 0.25 {C}o{O} 2.9 studied with
scattering methods and first-principle calculations},
journal = {Physical review / B},
volume = {104},
number = {14},
issn = {1098-0121},
address = {Woodbury, NY},
publisher = {Inst.},
reportid = {FZJ-2021-05936},
pages = {144107},
year = {2021},
abstract = {We studied structural and magnetic phase transitions under
applied pressure for the doped cobaltite La0.75Ba0.25CoO2.9.
Neutron and x-ray diffraction experiments established the
coexistence of rhombohedral and cubic phases in the sample.
The magnetic state at 2 K is best described as a long-range
ordered antiferromagnet (AFM) with small ferromagnetic (FM)
clusters. With application of pressure, the rhombohedral
phase gradually transforms into a cubic one. At room
temperature and the highest applied pressure of 16 GPa, the
cubic phase accounts for $70\%$ of the sample volume.
Quantum mechanical modeling confirmed the experimental
findings and provided more insights into the structural and
magnetic phase transitions at pressures exceeding 16 GPa.
While the cubic crystal structure was preserved above 10
GPa, the AFM to FM phase transition was found at around 16
GPa. Further increase of the pressure resulted in
suppression of magnetic order above 45 GPa. Using density
functional theory (DFT)+U calculations, we were able to
relate macroscopic magnetic properties induced by pressure
with corresponding spin-state transitions in Co ions.},
cin = {IBI-8 / JCNS-1},
ddc = {530},
cid = {I:(DE-Juel1)IBI-8-20200312 / I:(DE-Juel1)JCNS-1-20110106},
pnm = {633 - Life Sciences – Building Blocks of Life: Structure
and Function (POF4-633) / 5251 - Multilevel Brain
Organization and Variability (POF4-525) / 5241 - Molecular
Information Processing in Cellular Systems (POF4-524) / 6G4
- Jülich Centre for Neutron Research (JCNS) (FZJ)
(POF4-6G4)},
pid = {G:(DE-HGF)POF4-633 / G:(DE-HGF)POF4-5251 /
G:(DE-HGF)POF4-5241 / G:(DE-HGF)POF4-6G4},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000707470400001},
doi = {10.1103/PhysRevB.104.144107},
url = {https://juser.fz-juelich.de/record/904366},
}