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@ARTICLE{Qi:904945,
author = {Qi, Rui and Chu, Mihai and Zhao, Wenguang and Liao, Lei and
Chen, Ziwei and Zheng, Shisheng and Chen, Xiping and Xie,
Lei and Liu, Tongchao and Ren, Yang and Jin, Lei and Amine,
Khalil and Pan, Feng and Xiao, Yinguo},
title = {{A} highly-stable layered {F}e/{M}n-based cathode with
ultralow strain for advanced sodium-ion batteries},
journal = {Nano energy},
volume = {88},
issn = {2211-2855},
address = {Amsterdam [u.a.]},
publisher = {Elsevier},
reportid = {FZJ-2022-00259},
pages = {106206 -},
year = {2021},
abstract = {Sodium-ion batteries (SIBs) with iron- and manganese-based
cathode electrodes have exhibited great promise in the
grid-scale energy storage systems, on the basis of the
satisfactory theoretical capacity, as well as huge
abundance, low price and non-toxicity of raw materials.
However, the inferior cycle life of cathode materials
originating from their poor structural stability remains a
formidable challenge towards practical applications. Here,
an efficient strategy of improving the structure durability
is demonstrated in iron- and manganese-based cathodes by
dual heteroatom doping. The as-obtained P2-type
Na0.65Li0.08Cu0.08Fe0.24Mn0.6O2 cathode delivers superior
cyclability $(88.2\%$ capacity retention for 500 cycles at
2C), fabulous rate capability $(76\%$ capacity retention at
5C compared to 0.1C), and a useable reversible capacity of
around 85 mAh g−1 at 0.1C. Through in-depth
characterizations, the underlying structure-property
relationship is established, revealing that the complete
solid-solution reaction during cycling ensures the ultralow
volume variation (as small as $0.7\%)$ and excellent
electrochemical performance. These results highlight the
significance of fabricating a stable host for the design and
development of advanced SIBs with long life.},
cin = {ER-C-1},
ddc = {660},
cid = {I:(DE-Juel1)ER-C-1-20170209},
pnm = {5351 - Platform for Correlative, In Situ and Operando
Characterization (POF4-535)},
pid = {G:(DE-HGF)POF4-5351},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000702538600002},
doi = {10.1016/j.nanoen.2021.106206},
url = {https://juser.fz-juelich.de/record/904945},
}