000904952 001__ 904952
000904952 005__ 20240712113053.0
000904952 0247_ $$2doi$$a10.3390/batteries7020041
000904952 0247_ $$2Handle$$a2128/29985
000904952 0247_ $$2altmetric$$aaltmetric:108166570
000904952 0247_ $$2WOS$$aWOS:000665176500001
000904952 037__ $$aFZJ-2022-00266
000904952 082__ $$a530
000904952 1001_ $$0P:(DE-Juel1)139534$$aMöller, Sören$$b0$$eCorresponding author
000904952 245__ $$aAbsolute Local Quantification of Li as Function of State-of-Charge in All-Solid-State Li Batteries via 2D MeV Ion-Beam Analysis
000904952 260__ $$aBasel$$bMDPI$$c2021
000904952 3367_ $$2DRIVER$$aarticle
000904952 3367_ $$2DataCite$$aOutput Types/Journal article
000904952 3367_ $$0PUB:(DE-HGF)16$$2PUB:(DE-HGF)$$aJournal Article$$bjournal$$mjournal$$s1641556286_18961
000904952 3367_ $$2BibTeX$$aARTICLE
000904952 3367_ $$2ORCID$$aJOURNAL_ARTICLE
000904952 3367_ $$00$$2EndNote$$aJournal Article
000904952 520__ $$aDirect observation of the lithiation and de-lithiation in lithium batteries on the component and microstructural scale is still difficult. This work presents recent advances in MeV ion-beam analysis, enabling quantitative contact-free analysis of the spatially-resolved lithium content and state-of-charge (SoC) in all-solid-state lithium batteries via 3 MeV proton-based characteristic x-ray and gamma-ray emission analysis. The analysis is demonstrated on cross-sections of ceramic and polymer all-solid-state cells with LLZO and MEEP/LIBOB solid electrolytes. Different SoC are measured ex-situ and one polymer-based operando cell is charged at 333 K during analysis. The data unambiguously show the migration of lithium upon charging. Quantitative lithium concentrations are obtained by taking the physical and material aspects of the mixed cathodes into account. This quantitative lithium determination as a function of SoC gives insight into irreversible degradation phenomena of all-solid-state batteries during the first cycles and locations of immobile lithium. The determined SoC matches the electrochemical characterization within uncertainties. The presented analysis method thus opens up a completely new access to the state-of-charge of battery cells not depending on electrochemical measurements. Automated beam scanning and data-analysis algorithms enable a 2D quantitative Li and SoC mapping on the µm-scale, not accessible with other methods.
000904952 536__ $$0G:(DE-HGF)POF4-1222$$a1222 - Components and Cells (POF4-122)$$cPOF4-122$$fPOF IV$$x0
000904952 536__ $$0G:(BMBF)03XP0124A$$aInDiCate - In-situ Analyse der Li-Verteilung in Kathoden (03XP0124A)$$c03XP0124A$$x1
000904952 536__ $$0G:(BMBF)13XP0173A$$aFestBatt-Oxide - Materialplattform 'Oxide' im Rahmen des Kompetenzclusters für Festkörperbatterien (13XP0173A)$$c13XP0173A$$x2
000904952 536__ $$0G:(BMBF)13XP0228D$$aInCa - Interfaces von Mischkathoden in Festkörperbatterien - Fortschrittliche Charakterisierung und Optimierung, Teilvorhaben: Fortschrittliche Ionenstrahlanalytik an Festkörperzellen (13XP0228D)$$c13XP0228D$$x3
000904952 588__ $$aDataset connected to CrossRef, Journals: juser.fz-juelich.de
000904952 7001_ $$0P:(DE-HGF)0$$aSatoh, Takahiro$$b1
000904952 7001_ $$0P:(DE-HGF)0$$aIshii, Yasuyuki$$b2
000904952 7001_ $$0P:(DE-HGF)0$$aTeßmer, Britta$$b3
000904952 7001_ $$0P:(DE-HGF)0$$aGuerdelli, Rayan$$b4
000904952 7001_ $$0P:(DE-HGF)0$$aKamiya, Tomihiro$$b5
000904952 7001_ $$0P:(DE-HGF)0$$aFujita, Kazuhisa$$b6
000904952 7001_ $$00000-0002-2473-0724$$aSuzuki, Kota$$b7
000904952 7001_ $$0P:(DE-HGF)0$$aKato, Yoshiaki$$b8
000904952 7001_ $$0P:(DE-Juel1)176785$$aWiemhöfer, Hans-Dieter$$b9$$ufzj
000904952 7001_ $$0P:(DE-HGF)0$$aMima, Kunioki$$b10
000904952 7001_ $$0P:(DE-Juel1)145623$$aFinsterbusch, Martin$$b11$$eCorresponding author$$ufzj
000904952 773__ $$0PERI:(DE-600)2813972-0$$a10.3390/batteries7020041$$gVol. 7, no. 2, p. 41 -$$n2$$p41 -$$tBatteries$$v7$$x2313-0105$$y2021
000904952 8564_ $$uhttps://juser.fz-juelich.de/record/904952/files/batteries-07-00041.pdf$$yOpenAccess
000904952 909CO $$ooai:juser.fz-juelich.de:904952$$pdnbdelivery$$pdriver$$pVDB$$popen_access$$popenaire
000904952 9101_ $$0I:(DE-588b)5008462-8$$6P:(DE-Juel1)139534$$aForschungszentrum Jülich$$b0$$kFZJ
000904952 9101_ $$0I:(DE-588b)5008462-8$$6P:(DE-Juel1)176785$$aForschungszentrum Jülich$$b9$$kFZJ
000904952 9101_ $$0I:(DE-588b)5008462-8$$6P:(DE-Juel1)145623$$aForschungszentrum Jülich$$b11$$kFZJ
000904952 9131_ $$0G:(DE-HGF)POF4-122$$1G:(DE-HGF)POF4-120$$2G:(DE-HGF)POF4-100$$3G:(DE-HGF)POF4$$4G:(DE-HGF)POF$$9G:(DE-HGF)POF4-1222$$aDE-HGF$$bForschungsbereich Energie$$lMaterialien und Technologien für die Energiewende (MTET)$$vElektrochemische Energiespeicherung$$x0
000904952 9141_ $$y2021
000904952 915__ $$0StatID:(DE-HGF)0200$$2StatID$$aDBCoverage$$bSCOPUS$$d2020-08-20
000904952 915__ $$0LIC:(DE-HGF)CCBY4$$2HGFVOC$$aCreative Commons Attribution CC BY 4.0
000904952 915__ $$0StatID:(DE-HGF)0501$$2StatID$$aDBCoverage$$bDOAJ Seal$$d2020-08-20
000904952 915__ $$0StatID:(DE-HGF)0112$$2StatID$$aWoS$$bEmerging Sources Citation Index$$d2020-08-20
000904952 915__ $$0StatID:(DE-HGF)0500$$2StatID$$aDBCoverage$$bDOAJ$$d2020-08-20
000904952 915__ $$0StatID:(DE-HGF)0150$$2StatID$$aDBCoverage$$bWeb of Science Core Collection$$d2020-08-20
000904952 915__ $$0StatID:(DE-HGF)0510$$2StatID$$aOpenAccess
000904952 915__ $$0StatID:(DE-HGF)0030$$2StatID$$aPeer Review$$bDOAJ : Blind peer review$$d2020-08-20
000904952 915__ $$0StatID:(DE-HGF)0561$$2StatID$$aArticle Processing Charges$$d2020-08-20
000904952 915__ $$0StatID:(DE-HGF)0700$$2StatID$$aFees$$d2020-08-20
000904952 915__ $$0StatID:(DE-HGF)0199$$2StatID$$aDBCoverage$$bClarivate Analytics Master Journal List$$d2020-08-20
000904952 920__ $$lyes
000904952 9201_ $$0I:(DE-Juel1)IEK-1-20101013$$kIEK-1$$lWerkstoffsynthese und Herstellungsverfahren$$x0
000904952 9201_ $$0I:(DE-Juel1)IEK-12-20141217$$kIEK-12$$lHelmholtz-Institut Münster Ionenleiter für Energiespeicher$$x1
000904952 9801_ $$aFullTexts
000904952 980__ $$ajournal
000904952 980__ $$aVDB
000904952 980__ $$aUNRESTRICTED
000904952 980__ $$aI:(DE-Juel1)IEK-1-20101013
000904952 980__ $$aI:(DE-Juel1)IEK-12-20141217
000904952 981__ $$aI:(DE-Juel1)IMD-4-20141217
000904952 981__ $$aI:(DE-Juel1)IMD-2-20101013