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@ARTICLE{Kindelmann:905372,
author = {Kindelmann, Moritz and Weber, Moritz Lukas and Stamminger,
Mark and Buschhaus, Rahel and Breuer, Uwe and Bram, Martin
and Guillon, Olivier},
title = {{P}rocessing map to control the erosion of {Y} 2 {O} 3 in
fluorine based etching plasmas},
journal = {Journal of the American Ceramic Society},
volume = {105},
number = {5},
issn = {0002-7820},
address = {Westerville, Ohio},
publisher = {Soc.},
reportid = {FZJ-2022-00625},
pages = {3498-3509},
year = {2022},
abstract = {Due to the increasing number of applications for ceramic
components in reactive etching processes, the interest in
the specific erosion behavior of highly etch-resistant
materials like yttrium oxide (Y2O3) has increased in the
past years. Despite the large number of investigations
already existing in this field, a more general understanding
of the erosion mechanisms still lacks due to the limited
comparability of these investigations. The huge difference
in the kind of etching setups, processing parameters (bias
voltage and plasma gas composition), and sample
microstructures prevented consistent conclusions so far. To
achieve a more general understanding, this study
investigates the erosion behavior Y2O3 under a broad
spectrum of plasma etching parameters. Therefore, the bias
voltage is increased from 50 to 300 V and the plasma gas
composition is gradually changed from Ar-rich to CF4-rich
compositions. This systematic approach allows to directly
correlate the morphology changes caused by plasma erosion
with the related plasma etching parameters and enables to
better understand their influence on the depth of physical
and chemical interactions, surface damage, and etching rate.
We discovered three distinct erosion regimes, which exhibit
specific erosion characteristics. Using these observations,
a schematic processing map for Y2O3 was developed, which
could help to estimate the severity of the erosion attack
dependent on the processing parameters.},
cin = {ER-C-2 / ZEA-3 / IEK-1 / PGI-7 / JARA-FIT},
ddc = {660},
cid = {I:(DE-Juel1)ER-C-2-20170209 / I:(DE-Juel1)ZEA-3-20090406 /
I:(DE-Juel1)IEK-1-20101013 / I:(DE-Juel1)PGI-7-20110106 /
$I:(DE-82)080009_20140620$},
pnm = {5353 - Understanding the Structural and Functional Behavior
of Solid State Systems (POF4-535) / 5233 - Memristive
Materials and Devices (POF4-523)},
pid = {G:(DE-HGF)POF4-5353 / G:(DE-HGF)POF4-5233},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000742762600001},
doi = {10.1111/jace.18334},
url = {https://juser.fz-juelich.de/record/905372},
}