TY  - EJOUR
AU  - Mennicken, Max
AU  - Peter, Sophia K
AU  - Kaulen, Corinna
AU  - Simon, Ulrich
AU  - Karthäuser, Silvia
TI  - Impact of device design on the electronic and optoelectronic properties of integrated Ru-terpyridine complexes
M1  - FZJ-2022-01140
PY  - 2021
AB  - The performance of nanoelectronic and molecular electronic devices relies strongly on the employed functional units and their addressability, which is often a matter of appropriate interfaces and device design. Here, we compare two promising designs to build up solid-state electronic devices utilizing the same functional unit. Optically addressable Ru-terpyridine complexes were incorporated in supramolecular wires or employed as ligands of gold nanoparticles and contacted by nanoelectrodes. The resulting small area nanodevices were thoroughly electrically characterized as a function of temperature and light exposure. Differences in the resulting device conductance could be attributed to the device design and the respective transport mechanism: thermally activated hopping conduction in case of Ru-terpyridine wire devices or sequential tunneling in nanoparticle-based devices. Furthermore, the conductance switching of nanoparticle-based devices upon 530 nm irradiation was attributed to plasmon-induced metal-to-ligand charge-transfer in the Ru-terpyridine complexes used as switching ligands. Finally, our results reveal a superior device performance of nanoparticle-based devices compared to molecular wire devices based on Ru-terpyridine complexes as functional units.
LB  - PUB:(DE-HGF)25
DO  - DOI:10.3762/bxiv.2021.78.v1
UR  - https://juser.fz-juelich.de/record/905959
ER  -