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@ARTICLE{Kiebach:906052,
      author       = {Kiebach, Ragnar and Pirou, Stéven and Martinez Aguilera,
                      Lev and Haugen, Astri Bjørnetun and Kaiser, Andreas and
                      Hendriksen, Peter Vang and Balaguer, María and
                      García-Fayos, Julio and Serra, José Manuel and
                      Schulze-Küppers, Falk and Christie, Max and Fischer,
                      Liudmila and Meulenberg, Wilhelm Albert and Baumann, Stefan},
      title        = {{A} review on dual-phase oxygen transport membranes: from
                      fundamentals to commercial deployment},
      journal      = {Journal of materials chemistry / A},
      volume       = {10},
      number       = {5},
      issn         = {2050-7488},
      address      = {London ˜[u.a.]œ},
      publisher    = {RSC},
      reportid     = {FZJ-2022-01198},
      pages        = {2152-2195},
      year         = {2022},
      abstract     = {Oxygen transport membranes (OTMs) are a promising
                      alternative to cryogenic air separation (ASU) or pressure
                      swing adsorption (PSA) for oxygen production. Using these
                      ceramic membranes allows producing high purity oxygen on
                      various scales in a continuous single-step process, at lower
                      costs and power consumption, making it an advantageous
                      technique for oxy-combustion in connection with carbon
                      capture and delocalized oxygen production on a small scale.
                      Moreover, their use in membrane reactors, directly utilizing
                      the permeating oxygen in chemical reactions towards green
                      chemistry, is an emerging research field. Especially
                      dual-phase OTMs, where the membrane consists of a composite
                      of a stable ionic conductor and a stable electronic
                      conductor, are of high interest, because they can overcome
                      the disadvantages of single-phase membranes like low
                      chemical and mechanical stability at elevated temperatures
                      and under harsh operation conditions. However, despite the
                      progress in the development of dual-phase OTMs over the last
                      years, and their potential applications in classic and
                      emerging fields, challenges preventing their large-scale
                      employment remain. This review aims to guide new studies
                      that will promote the development and upscaling of
                      dual-phase OTMs. Recent developments, current opportunities
                      and challenges, and future directions of research are
                      thoroughly discussed. Through this review paper, information
                      about the basic working principle, properties, performance
                      and current application in industry of dual-phase OTM
                      membranes can be comprehended. Next to material properties,
                      preparative methods and manufacturing are in focus,
                      intending to accelerate development and upscaling of new
                      materials and components. Furthermore, existing challenges
                      and research strategies to overcome these are discussed, and
                      focus areas and prospects of future application areas are
                      suggested.},
      cin          = {IEK-1},
      ddc          = {530},
      cid          = {I:(DE-Juel1)IEK-1-20101013},
      pnm          = {1232 - Power-based Fuels and Chemicals (POF4-123) / DFG
                      project 387282673 - Die Rolle von Grenzflächen in
                      mehrphasigen Ceroxid-basierten Membranen für den Einsatz in
                      Membranreaktoren},
      pid          = {G:(DE-HGF)POF4-1232 / G:(GEPRIS)387282673},
      typ          = {PUB:(DE-HGF)16},
      UT           = {WOS:000743179700001},
      doi          = {10.1039/D1TA07898D},
      url          = {https://juser.fz-juelich.de/record/906052},
}