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000906268 1001_ $$0P:(DE-Juel1)180280$$aLu, Xin$$b0$$ufzj
000906268 245__ $$aTuning the moisture stability of multiphase β‐Li 3 PS 4 solid electrolyte materials
000906268 260__ $$aWeinheim$$bWiley-VCH Verlag GmbH & Co KGaA$$c2022
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000906268 520__ $$aEfficiently improving the moisture stability of β-Li3PS4 materials could significantly reduce production costs and eventually enable the mass application. Nanoporous multiphase β-Li3PS4 materials prepared via solvent-assistant routes usually contain solvent or solvent decomposition segments associated with the amorphous Li3PS4 phase in their structures. Herein, the solvent ethyl propionate (EP) remains in the β-Li3PS4 even after 220 h of annealing at 220°C. The possibility of tuning the moisture stability of β-Li3PS4 by adjusting the content of the solvent is investigated by environmental scanning electron microscopy (ESEM) combined with other structural analysis techniques. The results demonstrated that the hydrogen-containing amorphous Li3PS4 not only stabilizes the β-phase at room temperature but also improves the moisture stability of the material. Although the rapid hydrolysis occurs on the surface of solvent-containing β-Li3PS4 materials under ambient conditions within 10 s, with 4 wt% EP content, the material can be exposed to 1.6% relative humidity (R.H.) for at least 8 h without any structural or microstructural change. Even with the lower amount of EP (1.2 wt%) in the Li3PS4 structure, the material can withstand 1% R.H. for more than 8 h, which allows the material to be manufactured in a dry room. Our observation proposes a simple method to slightly modify the moisture stability of β-Li3PS4 to match the different manufacturing conditions.
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000906268 7001_ $$0P:(DE-Juel1)180631$$aCamara, Osmane$$b1$$ufzj
000906268 7001_ $$0P:(DE-Juel1)172733$$aLiu, Zigeng$$b2$$ufzj
000906268 7001_ $$0P:(DE-Juel1)188297$$aWindmüller, Anna$$b3$$ufzj
000906268 7001_ $$0P:(DE-Juel1)156244$$aTsai, Chih-Long$$b4$$ufzj
000906268 7001_ $$0P:(DE-Juel1)161208$$aTempel, Hermann$$b5$$ufzj
000906268 7001_ $$0P:(DE-Juel1)161141$$aYu, Shicheng$$b6$$eCorresponding author
000906268 7001_ $$0P:(DE-Juel1)157700$$aKungl, Hans$$b7$$ufzj
000906268 7001_ $$0P:(DE-Juel1)156123$$aEichel, Rüdiger-A.$$b8$$ufzj
000906268 773__ $$0PERI:(DE-600)2984616-X$$a10.1002/elsa.202100208$$n2$$pe2100208$$tElectrochemical science advances$$v3$$x2698-5977$$y2022
000906268 8564_ $$uhttps://juser.fz-juelich.de/record/906268/files/Electrochemical%20Science%20Adv%20-%202022%20-%20Lu%20-%20Tuning%20the%20moisture%20stability%20of%20multiphase%20%E2%80%90Li3PS4%20solid%20electrolyte%20materials.pdf$$yOpenAccess
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