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@ARTICLE{Mohanakumar:906314,
      author       = {Mohanakumar, Shilpa and Wiegand, Simone},
      title        = {{T}owards understanding specific ion effects in aqueous
                      media using thermodiffusion},
      journal      = {The European physical journal / E},
      volume       = {45},
      number       = {2},
      issn         = {1292-8941},
      address      = {Heidelberg},
      publisher    = {Springer},
      reportid     = {FZJ-2022-01364},
      pages        = {10},
      year         = {2022},
      abstract     = {Specific ion effects play an important role in scientific
                      and technological processes. According to Hofmeister, the
                      influence on the hydrogen bond network depends on the ion
                      and leads to a specific order of the ions. Also
                      thermodiffusion the mass transport caused by a temperature
                      gradient is very sensitive to changes of the hydrogen bond
                      network leading to a ranking according to hydrophilicity of
                      the salt. Hence, we investigate various salt solutions in
                      order to compare with the Hofmeister concept. We have
                      studied three different sodium salts in water as a function
                      of temperature (25 to 45°C) and concentration (0.5-5
                      mol/kg) using Thermal Diffusion Forced Rayleigh Scattering
                      (TDFRS). The three anions studied, carbonate, acetate and
                      $\textcolor{red}{thiocyanate},$ span the entire range of the
                      Hofmeister series from hydrophilic to hydrophobic. We
                      compare the results with the recent measurements of the
                      corresponding potassium salts to see to what extent the
                      cation changes the thermodiffusion of the salt.},
      cin          = {IBI-4},
      ddc          = {530},
      cid          = {I:(DE-Juel1)IBI-4-20200312},
      pnm          = {5241 - Molecular Information Processing in Cellular Systems
                      (POF4-524)},
      pid          = {G:(DE-HGF)POF4-5241},
      typ          = {PUB:(DE-HGF)16},
      pubmed       = {35106668},
      UT           = {WOS:000749516500001},
      doi          = {10.1140/epje/s10189-022-00164-8},
      url          = {https://juser.fz-juelich.de/record/906314},
}