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024 7 _ |a 10.3390/molecules27041241
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024 7 _ |a 2128/32088
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100 1 _ |a Sondermann, Linda
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245 _ _ |a Nickel-Based Metal-Organic Frameworks as Electrocatalysts for the Oxygen Evolution Reaction (OER)
260 _ _ |a Basel
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520 _ _ |a The exploration of earth-abundant electrocatalysts with high performance for the oxygen evolution reaction (OER) is eminently desirable and remains a significant challenge. The composite of the metal-organic framework (MOF) Ni10Co-BTC (BTC = 1,3,5-benzenetricarboxylate) and the highly conductive carbon material ketjenblack (KB) could be easily obtained from the MOF synthesis in the presence of KB in a one-step solvothermal reaction. The composite and the pristine MOF perform better than commercially available Ni/NiO nanoparticles under the same conditions for the OER. Activation of the nickel-cobalt clusters from the MOF can be seen under the applied anodic potential, which steadily boosts the OER performance. Ni10Co-BTC and Ni10Co-BTC/KB are used as sacrificial agents and undergo structural changes during electrochemical measurements, the stabilized materials show good OER performances.
536 _ _ |a 1231 - Electrochemistry for Hydrogen (POF4-123)
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700 1 _ |a Jiang, Wulv
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700 1 _ |a Shviro, Meital
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700 1 _ |a Spieß, Alex
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700 1 _ |a Woschko, Dennis
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700 1 _ |a Rademacher, Lars
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700 1 _ |a Janiak, Christoph
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773 _ _ |a 10.3390/molecules27041241
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