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@ARTICLE{Borzutzki:906508,
      author       = {Borzutzki, Kristina and Nair, Jijeesh Ravi and Winter,
                      Martin and Brunklaus, Gunther},
      title        = {{D}oes {C}ell {P}olarization {M}atter in {S}ingle-{I}on
                      {C}onducting {E}lectrolytes?},
      journal      = {ACS applied materials $\&$ interfaces},
      volume       = {14},
      number       = {4},
      issn         = {1944-8244},
      address      = {Washington, DC},
      publisher    = {Soc.},
      reportid     = {FZJ-2022-01487},
      pages        = {5211 - 5222},
      year         = {2022},
      abstract     = {Single-ion conducting polymer electrolytes (SIPE) are
                      particularly promising electrolyte materials in lithium
                      metal-based batteries since theoretical considerations
                      suggest that the immobilization of anions avoids
                      polarization phenomena at electrode|electrolyte interfaces.
                      SIPE in principle could allow for fast charging while
                      preventing cell failure induced by short circuits arising
                      from the growth of inhomogeneous Li depositions provided
                      that SIPE membranes possess sufficient mechanical stability.
                      To date, different chemical structures are developed for
                      SIPE, where new compounds are often reported through
                      electrochemical characterization at low current rates.
                      Experimental counterparts to model-based assumptions and
                      determination of system limitations by correlating both
                      models and experiments are rare in the literature. Herein,
                      Chazalviel’s model, which is derived from ion
                      concentration gradients, is applied to theoretically
                      determine the limiting current density (JLim) of a SIPE.
                      Comparison with the experimentally obtained JLim reveals a
                      large deviation between the theoretical and practical
                      values. Beyond that, charge–discharge profiles show a
                      distinct arcing behavior at moderate current densities (0.5
                      to 1 mA cm–2), indicating polarization of the cell, which
                      is not so far reported for SIPE. In this context, by
                      application of various electrochemical and physiochemical
                      methods, the details of cell polarization and the role of
                      the solid electrolyte interphase in producing arcing
                      behavior in the voltage profiles in stripping/plating
                      experiments are revealed, which eventually also elucidate
                      the inconsistency of JLim.},
      cin          = {IEK-12},
      ddc          = {600},
      cid          = {I:(DE-Juel1)IEK-12-20141217},
      pnm          = {1221 - Fundamentals and Materials (POF4-122)},
      pid          = {G:(DE-HGF)POF4-1221},
      typ          = {PUB:(DE-HGF)16},
      pubmed       = {pmid:35072445},
      UT           = {WOS:000757815700001},
      doi          = {10.1021/acsami.1c19097},
      url          = {https://juser.fz-juelich.de/record/906508},
}