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@ARTICLE{Du:906509,
      author       = {Du, Leilei and Hou, Xu and Yang, Xiaofei and Siozios,
                      Vassilios and Yan, Bo and Ju, Xiangkang and Paillard, Elie
                      and Winter, Martin and Placke, Tobias and Li, Jie},
      title        = {{D}endrite‐{F}ree {Z}inc {D}eposition {I}nduced by {Z}inc
                      {P}hytate {C}oating for {L}ong‐life {A}queous {Z}inc
                      {B}atteries},
      journal      = {Batteries $\&$ supercaps},
      volume       = {5},
      number       = {6},
      issn         = {2566-6223},
      address      = {Weinheim},
      publisher    = {Wiley-VCH},
      reportid     = {FZJ-2022-01488},
      pages        = {e202100376},
      year         = {2022},
      abstract     = {Rechargeable aqueous zinc batteries (AZBs) have been
                      recognized as attractive energy storage devices because of
                      their intrinsic superiorities, e.g., high safety, low
                      material cost and environmental benignity. However,
                      challenges such as dendrite formation on the surface of Zn
                      anode, poor reversibility of Zn plating/stripping and short
                      circuit of the cell, having detrimental impact on cycle life
                      and safety, hinder their further development. Herein, we
                      design an artificial solid electrolyte interphase (SEI)
                      layer for the Zn anode by coating it with a zinc phytate
                      (ZP) layer via a facile acid-etching approach. Since the ZP
                      layer can guide uniform Zn deposition under the layer
                      without dendrite formation and maintain a smooth interface
                      between separator and electrode, the symmetric cell with a
                      modified Zn electrode exhibits excellent cycling stability
                      and low polarization voltage. Moreover, compared to the full
                      cell employing a bare Zn anode (MnO 2 /carbon nanofibers
                      (CNFs) || Zn), the one with modified Zn anode (MnO 2 /CNFs
                      || ZP-Zn) delivers much better long-term cycling stability
                      with a capacity retention of $80.2\%$ after 1000 cycles a
                      0.5 A g -1 . The coating via acid etching method offers a
                      practical technique for further development of AZBs.},
      cin          = {IEK-12},
      ddc          = {620},
      cid          = {I:(DE-Juel1)IEK-12-20141217},
      pnm          = {1221 - Fundamentals and Materials (POF4-122)},
      pid          = {G:(DE-HGF)POF4-1221},
      typ          = {PUB:(DE-HGF)16},
      UT           = {WOS:000772902700001},
      doi          = {10.1002/batt.202100376},
      url          = {https://juser.fz-juelich.de/record/906509},
}