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@PHDTHESIS{Shi:906542,
author = {Shi, Yan},
title = {{S}tationary and {T}ransient {B}ehaviour of {P}olymer
{E}lectrolyte {F}uel {C}ells},
volume = {567},
school = {RWTH Aachen},
type = {Dissertation},
address = {Jülich},
publisher = {Forschungszentrum Jülich GmbH Zentralbibliothek, Verlag},
reportid = {FZJ-2022-01506},
isbn = {978-3-95806-611-3},
series = {Schriften des Forschungszentrums Jülich. Reihe Energie
$\&$ Umwelt / Energy $\&$ Environment},
pages = {viii, 172 S.},
year = {2022},
note = {RWTH Aachen, Diss., 2021},
abstract = {The Low Temperature Polymer Electrolyte Fuel Cell (LT-PEFC)
is a promising alternative power source for automotive
applications that offers a relatively simple system level,
high efficiency, and completely harmless emissions. Fuel
cell operations are complex processes that can be influenced
by numerous different operating conditions. This thesis,
therefore, focuses on the analysis of the impact of
different operating conditions on, both static and dynamic
behavior of the LT-PEFC. An accuracy study is first
performed to evaluate the repeatability and reproducibility
of the in-house assembled LT-PEFCs employed in the
experiments. Four test cells are assembled and tested under
the same operating conditions. It is found that the
repeatability and reproducibility of the test cells are
better when higher stoichiometry ratios and lower current
density are applied in the tests. Overall, the LT-PEFCs used
in the experiments are characterized by a high level of
accuracy. Various operating parameters are considered in the
cell static behavior analysis. With the help of split-plot
design, cell orientation, cell temperature, cathodic
stoichiometric ratio and backpressure are determined to be
the most statistically significant factors for the cell
static behavior. Furthermore, the optimal cell performance
and corresponding parameter settings are determined via the
response surface methodology (RSM). Voltage overshoot and
undershoot behavior are used to characterize the cell
dynamic behavior. Using split-plot design, the load change
step, cell temperature, cathodic stoichiometric ratio and
backpressure are selected as the most significant factors
for both the voltage undershoot and overshoot behaviors.
Additionally, the effect of load change ramp on voltage
undershoot and overshoot is determined. The result suggests
that the load change with the ramp can significantly reduce
the undershoot and overshoot magnitudes. Moreover, the load
change with the ramp has a limited impacton the average
pressure drop and the ohmic resistance of the test cell.},
cin = {IEK-14},
cid = {I:(DE-Juel1)IEK-14-20191129},
pnm = {1231 - Electrochemistry for Hydrogen (POF4-123)},
pid = {G:(DE-HGF)POF4-1231},
typ = {PUB:(DE-HGF)3 / PUB:(DE-HGF)11},
urn = {urn:nbn:de:0001-2022040531},
url = {https://juser.fz-juelich.de/record/906542},
}