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000906701 037__ $$aFZJ-2022-01630
000906701 041__ $$aEnglish
000906701 1001_ $$0P:(DE-Juel1)130646$$aFrielinghaus, Henrich$$b0$$eCorresponding author$$ufzj
000906701 1112_ $$aQENS/WINS 2021$$cSan Sebastian$$d2021-05-17 - 2021-05-21$$gQENS/WINS 2021$$wSpain
000906701 245__ $$aIonic liquids in mild confinement
000906701 260__ $$c2021
000906701 3367_ $$033$$2EndNote$$aConference Paper
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000906701 520__ $$aThe structure and dynamics of the ionic liquid 1-ethyl-3-methylimidazolium acetate (EMIMAc) in porous glass with pores of the size 40 and 100 Å is determined in comparison to the bulk liquid. We employed x-ray diffraction to measure the domain structure, and neutron backscattering for the dynamics. In confinement, the liquid displays onion-like domain structuring while in bulk the liquid is largely forming a bicontinuous structure similar to microemulsions. This also has an effect on the dynamics of the liquid at high temperatures (373K): The ions in the bulk can diffuse along the domain boundaries while they need to cross the domains in the ordered state in confinement. At low temperatures, the attractive forces of all ions are such strong – we have a highly viscous fluid – such that the diffusion in any direction is similarly slow, and the exact domain structure plays a minor role.
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000906701 65017 $$0V:(DE-MLZ)GC-1602-2016$$2V:(DE-HGF)$$aPolymers, Soft Nano Particles and  Proteins$$x0
000906701 65017 $$0V:(DE-MLZ)GC-110$$2V:(DE-HGF)$$aEnergy$$x1
000906701 693__ $$0EXP:(DE-MLZ)SPHERES-20140101$$1EXP:(DE-MLZ)FRMII-20140101$$5EXP:(DE-MLZ)SPHERES-20140101$$6EXP:(DE-MLZ)NL6S-20140101$$aForschungs-Neutronenquelle Heinz Maier-Leibnitz $$eSPHERES: Backscattering spectrometer$$fNL6S$$x0
000906701 7001_ $$0P:(DE-Juel1)165355$$aNoferini, Daria$$b1
000906701 7001_ $$0P:(DE-Juel1)130718$$aHolderer, Olaf$$b2$$ufzj
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000906701 9131_ $$0G:(DE-HGF)POF4-632$$1G:(DE-HGF)POF4-630$$2G:(DE-HGF)POF4-600$$3G:(DE-HGF)POF4$$4G:(DE-HGF)POF$$aDE-HGF$$bForschungsbereich Materie$$lFrom Matter to Materials and Life$$vMaterials – Quantum, Complex and Functional Materials$$x1
000906701 9141_ $$y2022
000906701 920__ $$lyes
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