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000906948 0247_ $$2doi$$a10.1016/j.oceram.2022.100248
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000906948 041__ $$aEnglish
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000906948 1001_ $$0P:(DE-Juel1)168104$$aLiu, Yang$$b0
000906948 245__ $$aPerformance study of asymmetric oxygen transport membranes with vertically channelled pores by phase inversion tape casting
000906948 260__ $$aAmsterdam$$bElsevier$$c2022
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000906948 520__ $$aAsymmetric oxygen transport membranes have been extensively studied revealing the importance of the support porosity. In this study, asymmetric membranes with vertically channelled pores were prepared from Ba0.5Sr0.5(Co0.8Fe0.2)0.97Zr0.03O3-δ (BSCF-Z) by phase inversion tape casting. The rate-limiting effects of the membrane layer thickness, the support structure, and the activation layers were thoroughly analysed. This entails comparing the permeation rate of the samples with the membrane layer on different sides of the channelled supports. Pore tortuosity and computed permeability were evaluated from 3D-X-ray computed tomography and compared to previously reported asymmetric membranes prepared by tape-casting and freeze-drying. Due to a lower pore tortuosity, the channelled supports have an advantage in gas transport over the tape cast and freeze cast supports. However, this is compensated by a thicker membrane layer (∼54 μm) resulting in similar performance compared to the thinner membrane layers (∼20 μm) with freeze cast and tape cast supports.
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000906948 7001_ $$0P:(DE-Juel1)144726$$aWilkner, Kai$$b1$$ufzj
000906948 7001_ $$0P:(DE-Juel1)164278$$aUnije, Unoaku Victoria$$b2
000906948 7001_ $$0P:(DE-Juel1)129587$$aBaumann, Stefan$$b3$$eCorresponding author
000906948 7001_ $$0P:(DE-Juel1)129641$$aMücke, Robert$$b4$$ufzj
000906948 7001_ $$0P:(DE-Juel1)129660$$aSchulze-Küppers, Falk$$b5
000906948 7001_ $$0P:(DE-Juel1)161591$$aGuillon, Olivier$$b6$$ufzj
000906948 770__ $$aConductivity in ceramics
000906948 773__ $$0PERI:(DE-600)3023650-2$$a10.1016/j.oceram.2022.100248$$gVol. 9, p. 100248 -$$p100248 -$$tOpen ceramics$$v9$$x2666-5395$$y2022
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