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000906962 1001_ $$0P:(DE-Juel1)190231$$aZegke, Markus$$b0$$eCorresponding author
000906962 245__ $$aAmmonium Pertechnetate in Mixtures of Trifluoromethanesulfonic Acid and Trifluoromethanesulfonic Anhydride
000906962 260__ $$aWeinheim$$bWiley-VCH$$c2022
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000906962 520__ $$aAmmonium pertechnetate reacts in mixtures of trifluoromethanesulfonic anhydride and trifluoromethanesulfonic acid under final formation of ammonium pentakis(trifluoromethanesulfonato) oxidotechnetate(V), (NH4)2[TcO(OTf)5]. The reaction proceeds only at exact concentrations and under the exclusion of air and moisture via pertechnetyl trifluoromethanesulfonate, [TcO3(OTf)], and intermediate Tc(VI) species. 99Tc nuclear magnetic resonance (NMR) has been used to study the Tc(VII) compound and electron paramagnetic resonance (EPR), 99Tc NMR and X-ray absorption near-edge structure (XANES) experiments indicate the presence of the reduced technetium species. On moist air, (NH4)2[TcO(OTf)5] slowly hydrolyses under formation of the tetramericoxidotechnetate(V) (NH4)4[{TcO(TcO4)4}4] 10 H2O. Single crystal Xray crystallography was used to determine the solid state structures. Additionally, UV-vis and IR spectra and quantum chemical calculations confirm the identity of the species.
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000906962 7001_ $$00000-0002-4994-2125$$aGrödler, Dennis$$b1
000906962 7001_ $$0P:(DE-HGF)0$$aRoca Jungfer, Maximilian$$b2
000906962 7001_ $$00000-0003-0480-7568$$aHaseloer, Alexander$$b3
000906962 7001_ $$0P:(DE-HGF)0$$aKreuter, Meike$$b4
000906962 7001_ $$00000-0002-2918-0565$$aNeudörfl, Jörg M.$$b5
000906962 7001_ $$0P:(DE-HGF)0$$aSittel, Thomas$$b6
000906962 7001_ $$0P:(DE-HGF)0$$aJames, Christopher M.$$b7
000906962 7001_ $$00000-0002-0589-3616$$aRothe, Jörg$$b8
000906962 7001_ $$0P:(DE-HGF)0$$aAltmaier, Marcus$$b9
000906962 7001_ $$00000-0003-0093-9619$$aKlein, Axel$$b10
000906962 7001_ $$00000-0003-0950-8858$$aBreugst, Martin$$b11
000906962 7001_ $$00000-0002-1747-7927$$aAbram, Ulrich$$b12
000906962 7001_ $$0P:(DE-HGF)0$$aStrub, Erik$$b13
000906962 7001_ $$00000-0002-8864-4227$$aWickleder, Mathias S.$$b14
000906962 773__ $$0PERI:(DE-600)2011836-3$$a10.1002/anie.202113777$$gVol. 61, no. 3$$n3$$pe202113777$$tAngewandte Chemie / International edition$$v61$$x0570-0833$$y2022
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