Home > Publications database > Ammonium Pertechnetate in Mixtures of Trifluoromethanesulfonic Acid and Trifluoromethanesulfonic Anhydride > print

001     906962
005     20230123110609.0
024 7 _ |a 10.1002/anie.202113777
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024 7 _ |a 1521-3773
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100 1 _ |a Zegke, Markus
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245 _ _ |a Ammonium Pertechnetate in Mixtures of Trifluoromethanesulfonic Acid and Trifluoromethanesulfonic Anhydride
260 _ _ |a Weinheim
|c 2022
|b Wiley-VCH
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520 _ _ |a Ammonium pertechnetate reacts in mixtures of trifluoromethanesulfonic anhydride and trifluoromethanesulfonic acid under final formation of ammonium pentakis(trifluoromethanesulfonato) oxidotechnetate(V), (NH4)2[TcO(OTf)5]. The reaction proceeds only at exact concentrations and under the exclusion of air and moisture via pertechnetyl trifluoromethanesulfonate, [TcO3(OTf)], and intermediate Tc(VI) species. 99Tc nuclear magnetic resonance (NMR) has been used to study the Tc(VII) compound and electron paramagnetic resonance (EPR), 99Tc NMR and X-ray absorption near-edge structure (XANES) experiments indicate the presence of the reduced technetium species. On moist air, (NH4)2[TcO(OTf)5] slowly hydrolyses under formation of the tetramericoxidotechnetate(V) (NH4)4[{TcO(TcO4)4}4] 10 H2O. Single crystal Xray crystallography was used to determine the solid state structures. Additionally, UV-vis and IR spectra and quantum chemical calculations confirm the identity of the species.
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700 1 _ |a Grödler, Dennis
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700 1 _ |a Roca Jungfer, Maximilian
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700 1 _ |a Haseloer, Alexander
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700 1 _ |a Kreuter, Meike
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700 1 _ |a Neudörfl, Jörg M.
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700 1 _ |a Sittel, Thomas
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700 1 _ |a James, Christopher M.
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700 1 _ |a Rothe, Jörg
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700 1 _ |a Altmaier, Marcus
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700 1 _ |a Klein, Axel
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700 1 _ |a Breugst, Martin
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700 1 _ |a Abram, Ulrich
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700 1 _ |a Strub, Erik
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700 1 _ |a Wickleder, Mathias S.
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773 _ _ |a 10.1002/anie.202113777
|g Vol. 61, no. 3
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|t Angewandte Chemie / International edition
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856 4 _ |u https://juser.fz-juelich.de/record/906962/files/Angew%20Chem%20Int%20Ed%20-%202021%20-%20Zegke%20-%20Ammonium%20Pertechnetate%20in%20Mixtures%20of%20Trifluoromethanesulfonic%20Acid%20and.pdf
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