Gast ::
| Hauptseite > Publikationsdatenbank > UoC-3: A Metal–Organic Framework with an Anionic Framework Based on Uranyl UO 2 2+ Nodes and Partly Fluorinated Benzene-1,3,5-Tribenzoate Linkers > print |
| Hauptseite > Publikationsdatenbank > UoC-3: A Metal–Organic Framework with an Anionic Framework Based on Uranyl UO 2 2+ Nodes and Partly Fluorinated Benzene-1,3,5-Tribenzoate Linkers > print |
| 001 | 906979 | ||
| 005 | 20250513114625.0 | ||
| 024 | 7 | _ | |2 doi |a 10.1021/acs.cgd.1c01199 |
| 024 | 7 | _ | |2 ISSN |a 1528-7483 |
| 024 | 7 | _ | |2 ISSN |a 1528-7505 |
| 024 | 7 | _ | |2 Handle |a 2128/30953 |
| 024 | 7 | _ | |2 altmetric |a altmetric:119327548 |
| 024 | 7 | _ | |2 WOS |a WOS:000741655300001 |
| 037 | _ | _ | |a FZJ-2022-01792 |
| 082 | _ | _ | |a 540 |
| 100 | 1 | _ | |0 P:(DE-HGF)0 |a Christoffels, Ronja |b 0 |
| 245 | _ | _ | |a UoC-3: A Metal–Organic Framework with an Anionic Framework Based on Uranyl UO 2 2+ Nodes and Partly Fluorinated Benzene-1,3,5-Tribenzoate Linkers |
| 260 | _ | _ | |a Washington, DC |b ACS Publ. |c 2022 |
| 336 | 7 | _ | |2 DRIVER |a article |
| 336 | 7 | _ | |2 DataCite |a Output Types/Journal article |
| 336 | 7 | _ | |0 PUB:(DE-HGF)16 |2 PUB:(DE-HGF) |a Journal Article |b journal |m journal |s 1648560696_1497 |
| 336 | 7 | _ | |2 BibTeX |a ARTICLE |
| 336 | 7 | _ | |2 ORCID |a JOURNAL_ARTICLE |
| 336 | 7 | _ | |0 0 |2 EndNote |a Journal Article |
| 520 | _ | _ | |a The reaction of UO2(NO3)2·6H2O with partly fluorinated H3-3F-BTB (BTB3–: benzene-1,3,5-tribenzoate) in N,N-dimethylformamide (DMF) leads to the crystallization of the metal–organic framework (MOF) [(CH3)2NH2][UO2(3F-BTB)]·xDMF, named UoC-3 (UoC: University of Cologne). X-ray single-crystal structure analysis (Pnna, Z = 4) reveals that an anionic framework is formed, in which UO22+ nodes are connected by 3F-BTB3– ligands. Because of the fluorination of the inner ring of the linker, its three benzoate groups are tilted to an “out of plane” arrangement, which leads to the formation of a three-dimensional structure with large pores. This is in contrast to a known uranyl coordination polymer with the unfluorinated BTB3– linker, where an almost coplanar arrangement of the linker leads to graphene-like layers. The high porosity of UoC-3 was confirmed by N2 gas sorption measurements, resulting in SBET = 4844 m2/g. The charge compensating [(CH3)2NH2]+ cation is formed by hydrolysis of DMF. Direct addition of [(CH3)2NH2]Cl to the reaction carried out in ethanol/H2O (v:v, 5:1) leads to the same MOF but with lower crystallinity. When using solvents, which hydrolyze to larger cations (e.g., N,N-diethylformamide (DEF): [(C2H5)2NH2]+ and N,N-di(n-butyl)formamide (DBF): [(C4H9)2NH2]+), again the formation of UoC-3 was found, as confirmed by X-ray single-crystal analysis and X-ray powder diffraction. Thus, no templating effect was achieved with these cations. The exchange of the organic cations by K+ turned out to be successful, as revealed by XPS analysis. UoC-3 was also successfully tested to remove approximately 96% radioactive 137Cs+ from aqueous solutions (93% after one regeneration cycle) while retaining its crystal structure. |
| 536 | _ | _ | |0 G:(DE-HGF)POF4-5253 |a 5253 - Neuroimaging (POF4-525) |c POF4-525 |f POF IV |x 0 |
| 588 | _ | _ | |a Dataset connected to CrossRef, Journals: juser.fz-juelich.de |
| 700 | 1 | _ | |0 P:(DE-HGF)0 |a Breitenbach , Carinanée Stastny |b 1 |
| 700 | 1 | _ | |0 P:(DE-HGF)0 |a Weber, Jean Patrick |b 2 |
| 700 | 1 | _ | |0 P:(DE-HGF)0 |a Körtgen, Lisa |b 3 |
| 700 | 1 | _ | |0 P:(DE-HGF)0 |a Tobeck, Christian |b 4 |
| 700 | 1 | _ | |0 P:(DE-HGF)0 |a Wilhelm, Michael |b 5 |
| 700 | 1 | _ | |0 0000-0003-2765-2693 |a Mathur, Sanjay |b 6 |
| 700 | 1 | _ | |0 P:(DE-HGF)0 |a Neudörfl, Jörg-Martin |b 7 |
| 700 | 1 | _ | |0 P:(DE-HGF)0 |a Farid, Majied Sadegh Zadeh |b 8 |
| 700 | 1 | _ | |0 P:(DE-HGF)0 |a Maslo, Melisa |b 9 |
| 700 | 1 | _ | |0 P:(DE-HGF)0 |a Strub, Erik |b 10 |
| 700 | 1 | _ | |0 0000-0002-6511-6894 |a Ruschewitz, Uwe |b 11 |e Corresponding author |
| 773 | _ | _ | |0 PERI:(DE-600)2048329-6 |a 10.1021/acs.cgd.1c01199 |g Vol. 22, no. 1, p. 681 - 692 |n 1 |p 681 - 692 |t Crystal growth & design |v 22 |x 1528-7483 |y 2022 |
| 856 | 4 | _ | |u https://juser.fz-juelich.de/record/906979/files/Paper_UoC-3.pdf |y Published on 2021-12-17. Available in OpenAccess from 2022-12-17. |
| 856 | 4 | _ | |u https://juser.fz-juelich.de/record/906979/files/acs.cgd.1c01199.pdf |y Restricted |
| 909 | C | O | |o oai:juser.fz-juelich.de:906979 |p openaire |p open_access |p VDB |p driver |p dnbdelivery |
| 910 | 1 | _ | |0 I:(DE-588b)5008462-8 |6 P:(DE-HGF)0 |a Forschungszentrum Jülich |b 10 |k FZJ |
| 913 | 1 | _ | |0 G:(DE-HGF)POF4-525 |1 G:(DE-HGF)POF4-520 |2 G:(DE-HGF)POF4-500 |3 G:(DE-HGF)POF4 |4 G:(DE-HGF)POF |9 G:(DE-HGF)POF4-5253 |a DE-HGF |b Key Technologies |l Natural, Artificial and Cognitive Information Processing |v Decoding Brain Organization and Dysfunction |x 0 |
| 914 | 1 | _ | |y 2022 |
| 915 | _ | _ | |0 StatID:(DE-HGF)0530 |2 StatID |a Embargoed OpenAccess |
| 915 | _ | _ | |0 StatID:(DE-HGF)0113 |2 StatID |a WoS |b Science Citation Index Expanded |d 2021-02-02 |
| 915 | _ | _ | |0 StatID:(DE-HGF)0160 |2 StatID |a DBCoverage |b Essential Science Indicators |d 2021-02-02 |
| 915 | _ | _ | |0 StatID:(DE-HGF)0100 |2 StatID |a JCR |b CRYST GROWTH DES : 2021 |d 2022-11-16 |
| 915 | _ | _ | |0 StatID:(DE-HGF)0200 |2 StatID |a DBCoverage |b SCOPUS |d 2022-11-16 |
| 915 | _ | _ | |0 StatID:(DE-HGF)0300 |2 StatID |a DBCoverage |b Medline |d 2022-11-16 |
| 915 | _ | _ | |0 StatID:(DE-HGF)0600 |2 StatID |a DBCoverage |b Ebsco Academic Search |d 2022-11-16 |
| 915 | _ | _ | |0 StatID:(DE-HGF)0030 |2 StatID |a Peer Review |b ASC |d 2022-11-16 |
| 915 | _ | _ | |0 StatID:(DE-HGF)0199 |2 StatID |a DBCoverage |b Clarivate Analytics Master Journal List |d 2022-11-16 |
| 915 | _ | _ | |0 StatID:(DE-HGF)0150 |2 StatID |a DBCoverage |b Web of Science Core Collection |d 2022-11-16 |
| 915 | _ | _ | |0 StatID:(DE-HGF)1150 |2 StatID |a DBCoverage |b Current Contents - Physical, Chemical and Earth Sciences |d 2022-11-16 |
| 915 | _ | _ | |0 StatID:(DE-HGF)9900 |2 StatID |a IF < 5 |d 2022-11-16 |
| 920 | _ | _ | |l yes |
| 920 | 1 | _ | |0 I:(DE-Juel1)INM-5-20090406 |k INM-5 |l Nuklearchemie |x 0 |
| 980 | _ | _ | |a journal |
| 980 | _ | _ | |a VDB |
| 980 | _ | _ | |a UNRESTRICTED |
| 980 | _ | _ | |a I:(DE-Juel1)INM-5-20090406 |
| 980 | 1 | _ | |a FullTexts |
| Library | Collection | CLSMajor | CLSMinor | Language | Author |
|---|