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024 7 _ |a 10.1016/j.jeurceramsoc.2022.01.052
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037 _ _ |a FZJ-2022-01859
082 _ _ |a 660
100 1 _ |a Li, Xinfang
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245 _ _ |a Sealing behaviour of glass-based composites for oxygen transport membranes
260 _ _ |a Amsterdam [u.a.]
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520 _ _ |a In this study, seven different filler materials in different proportions were added to a Ba-Ca-Si glass matrix “H” to investigate new sealant with higher thermal expansion coefficient (CTE) value and good sealing performance for application in oxygen transport membrane (OTM). SrTi0.75Fe0.25O3-δ (STF25) was used as an OTM, and the sealing partners were ferritic steel Aluchrom and pre-oxidized Aluchrom. Compatibility tests were carried out to investigate the feasibility of the composites. Higher CTE values were found in dilatometer tests on composite samples by adding 40 wt% Ag (HAg40) and 30 wt% Ni-Cr (HNC30). Gas-tightness measurements of sandwiched samples produced appropriate helium leakage rates in the range of 10−6 mbar·l·s−1. Sealing behaviour of sealants HAg40 and HNC30 were investigated by joining STF25 and as-delivered/pre-oxidized Aluchrom together. Scanning electron microscopy (SEM) on cross-sections of the joints revealed a homogeneous microstructure and good adherence of the glass sealants to support metals and STF25.
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700 1 _ |a Groß-Barsnick, Sonja M.
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700 1 _ |a Koppitz, Thomas
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700 1 _ |a Baumann, Stefan
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700 1 _ |a Meulenberg, Wilhelm A.
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700 1 _ |a Natour, Ghaleb
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773 _ _ |a 10.1016/j.jeurceramsoc.2022.01.052
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|t Journal of the European Ceramic Society
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856 4 _ |y Published on 2022-01-31. Available in OpenAccess from 2024-01-31.
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