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@ARTICLE{Denneulin:907141,
author = {Denneulin, T. and Everhardt, A. S.},
title = {{A} transmission electron microscopy study of low-strain
epitaxial {B}a{T}i{O} 3 grown onto {N}d{S}c{O} 3},
journal = {Journal of physics / Condensed matter},
volume = {34},
number = {23},
issn = {0953-8984},
address = {Bristol},
publisher = {IOP Publ.},
reportid = {FZJ-2022-01864},
pages = {235701},
year = {2022},
abstract = {Ferroelectric materials exhibit a strong coupling between
strain and electrical polarization. In epitaxial thin films,
the strain induced by the substrate can be used to tune the
domain structure. Substrates of rare-earth scandates are
sometimes selected for the growth of ferroelectric oxides
because of their close lattice match, which allows the
growth of low-strain dislocation-free layers. Transmission
electron microscopy (TEM) is a frequently used technique for
investigating ferroelectric domains at the nanometer-scale.
However, it requires to thin the specimen down to electron
transparency, which can modify the strain and the
electrostatic boundary conditions. Here, we have
investigated a 320 nm thick epitaxial layer of BaTiO3 grown
onto an orthorhombic substrate of NdScO3 with interfacial
lattice strains of $−0.45\%$ and $−0.05\%$ along the two
in-plane directions. We show that the domain structure of
the layer can be significantly altered by TEM sample
preparation depending on the orientation and the geometry of
the lamella. In the as-grown state, the sample shows an
anisotropic a/c ferroelastic domain pattern in the direction
of largest strain. If a TEM lamella is cut perpendicular to
this direction so that strain is released, a new domain
pattern is obtained, which consists of bundles of thin
horizontal stripes parallel to the interfaces. These stripe
domains correspond to a sheared crystalline structure
(orthorhombic or monoclinic) with inclined polarization
vectors and with at least four variants of polarization. The
stripe domains are distributed in triangular-shaped 180°
domains where the average polarization is parallel to the
growth direction. The influence of external electric fields
on this domain structure was investigated using in situ
biasing and dark-field imaging in TEM.},
cin = {ER-C-1},
ddc = {530},
cid = {I:(DE-Juel1)ER-C-1-20170209},
pnm = {5351 - Platform for Correlative, In Situ and Operando
Characterization (POF4-535)},
pid = {G:(DE-HGF)POF4-5351},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000778395400001},
doi = {10.1088/1361-648X/ac5db3},
url = {https://juser.fz-juelich.de/record/907141},
}