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005     20240711085703.0
024 7 _ |a 10.1016/j.ssi.2022.115918
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024 7 _ |a 0167-2738
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024 7 _ |a 1872-7689
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024 7 _ |a 2128/31064
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037 _ _ |a FZJ-2022-01876
082 _ _ |a 530
100 1 _ |a Leonard, Kwati
|0 P:(DE-Juel1)172676
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|e Corresponding author
245 _ _ |a Anode supported planar 5 × 5 cm2 SrZr0.5Ce0.4Y0.1O2.95 based solid oxide protonic fuel cells via sequential tape-casting
260 _ _ |a Amsterdam [u.a.]
|c 2022
|b Elsevier Science
336 7 _ |a article
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520 _ _ |a Solid oxide protonic fuel cells are one of the most efficient means of directly converting stored chemical energy to usable electrical energy. Acceptor-doped Ba(Zr, Ce)O3 perovskite-type oxides are the preferred electrolyte choice as they provide higher conductivity due to lower activation energy. While substantial progress has been made on small-sized protonic laboratory-scale cells, a considerable challenge has been upscaling robust planar-type devices. This paper employs a cost-effective inverse tape casting route and screen printing to fabricate flat planar anode-supported protonic fuel cells consisting of NiO-SrZr0.5Ce0.4Y0.1O3-δ substrate, SrZr0.5Ce0.4Y0.1O3-δ electrolyte, and BaCo0.4Fe0.4Zr0.1Y 0.1O3-δ as the cathode. The processing parameters were analyzed and adjusted to obtain defect-free single cells of dimension up to 100 mm × 100 mm × 0.5 mm with diminished warping. In addition, the smooth tri-layered green tapes yielded suitably dense and gas-tight electrolyte layers after co-sintering at 1300 °C/5 h. Finally, the electrochemical performance of the 50 × 50 mm2 SrZr0.5Ce0.4Y0.1O2.95 based cells was evaluated, and their impedance spectra were deconvoluted to identify all performance-related polarization processes via the distribution of relaxation time.
536 _ _ |a 1232 - Power-based Fuels and Chemicals (POF4-123)
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700 1 _ |a Ivanova, Mariya E.
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700 1 _ |a Weber, André
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700 1 _ |a Deibert, Wendelin
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700 1 _ |a Meulenberg, Wilhelm A.
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700 1 _ |a Ishihara, Tatsumi
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700 1 _ |a Matsumoto, Hiroshige
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773 _ _ |a 10.1016/j.ssi.2022.115918
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|t Solid state ionics
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856 4 _ |y Restricted
|u https://juser.fz-juelich.de/record/907171/files/1-s2.0-S0167273822000674-main.pdf
856 4 _ |y Published on 2022-04-07. Available in OpenAccess from 2024-04-07.
|u https://juser.fz-juelich.de/record/907171/files/Manuscript%20file.pdf
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