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000907232 1001_ $$0P:(DE-HGF)0$$aKobertz, D.$$b0$$eCorresponding author
000907232 245__ $$aVaporization Studies on Mn-Doped Lead Titanate
000907232 260__ $$aAmsterdam [u.a.]$$bElsevier Science$$c2022
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000907232 520__ $$aThermodynamic studies of a single crystal lead titanate (PbTiO3) doped with manganese (Mn) under equilibrium conditions by the method of Knudsen Effusion Mass Spectrometry (KEMS) were conducted in the temperature range 950–1250 K. The vaporization of pure PbO(c) was investigated at temperatures of 810–1040 K. The ferro-paraelectric phase change at 763 K is supposed to be classified as a continuous transition. The thermodynamic activity lead oxide was higher in a Mn-doped PbTiO3 (stability was lower than in pure PbTiO3). Titanium (Ti) was replaced by manganese (Mn) in the perovskite structure within the solubility range, and lead (Pb) was certainly not replaced. PbTiO3:Mn(c) showed long-term stability nearby the ferroelectric-paraelectric phase transition. The ferroelectric-paraelectric phase transition at 763 K is supposed to be classified as a continuous transition.
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000907232 7001_ $$0P:(DE-Juel1)129765$$aMüller, Michael$$b1
000907232 7001_ $$0P:(DE-HGF)0$$aMolakb, Andrzej$$b2
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000907232 8564_ $$uhttps://juser.fz-juelich.de/record/907232/files/Vaporizaton%20studies%20on%20-%20Kobertz.pdf$$yPublished on 2022-04-04. Available in OpenAccess from 2024-04-04.
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