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@ARTICLE{Kobertz:907232,
      author       = {Kobertz, D. and Müller, Michael and Molakb, Andrzej},
      title        = {{V}aporization {S}tudies on {M}n-{D}oped {L}ead {T}itanate},
      journal      = {Calphad},
      volume       = {77},
      issn         = {0364-5916},
      address      = {Amsterdam [u.a.]},
      publisher    = {Elsevier Science},
      reportid     = {FZJ-2022-01911},
      pages        = {102422},
      year         = {2022},
      abstract     = {Thermodynamic studies of a single crystal lead titanate
                      (PbTiO3) doped with manganese (Mn) under equilibrium
                      conditions by the method of Knudsen Effusion Mass
                      Spectrometry (KEMS) were conducted in the temperature range
                      950–1250 K. The vaporization of pure PbO(c) was
                      investigated at temperatures of 810–1040 K. The
                      ferro-paraelectric phase change at 763 K is supposed to be
                      classified as a continuous transition. The thermodynamic
                      activity lead oxide was higher in a Mn-doped PbTiO3
                      (stability was lower than in pure PbTiO3). Titanium (Ti) was
                      replaced by manganese (Mn) in the perovskite structure
                      within the solubility range, and lead (Pb) was certainly not
                      replaced. PbTiO3:Mn(c) showed long-term stability nearby the
                      ferroelectric-paraelectric phase transition. The
                      ferroelectric-paraelectric phase transition at 763 K is
                      supposed to be classified as a continuous transition.},
      cin          = {IEK-2},
      ddc          = {540},
      cid          = {I:(DE-Juel1)IEK-2-20101013},
      pnm          = {1243 - Thermal Energy Storage (POF4-124)},
      pid          = {G:(DE-HGF)POF4-1243},
      typ          = {PUB:(DE-HGF)16},
      UT           = {WOS:000866440900004},
      doi          = {10.1016/j.calphad.2022.102422},
      url          = {https://juser.fz-juelich.de/record/907232},
}