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000907456 1001_ $$00000-0002-3842-8286$$aYang, Dawei$$b0
000907456 245__ $$aA High Conductivity 1D π–d Conjugated Metal–Organic Framework with Efficient Polysulfide Trapping‐Diffusion‐Catalysis in Lithium–Sulfur Batteries
000907456 260__ $$aWeinheim$$bWiley-VCH$$c2022
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000907456 520__ $$aThe shuttling behavior and sluggish conversion kinetics of the intermediate lithium polysulfides (LiPS) represent the main obstructions to the practical application of lithium–sulfur batteries (LSBs). Herein, a 1D π–d conjugated metal–organic framework (MOF), Ni-MOF-1D, is presented as an efficient sulfur host to overcome these limitations. Experimental results and density functional theory calculations demonstrate that Ni-MOF-1D is characterized by a remarkable binding strength for trapping soluble LiPS species. Ni-MOF-1D also acts as an effective catalyst for S reduction during the discharge process and Li2S oxidation during the charging process. In addition, the delocalization of electrons in the π–d system of Ni-MOF-1D provides a superior electrical conductivity to improve electron transfer. Thus, cathodes based on Ni-MOF-1D enable LSBs with excellent performance, for example, impressive cycling stability with over 82% capacity retention over 1000 cycles at 3 C, superior rate performance of 575 mAh g−1 at 8 C, and a high areal capacity of 6.63 mAh cm−2 under raised sulfur loading of 6.7 mg cm−2. The strategies and advantages here demonstrated can be extended to a broader range of π–d conjugated MOFs materials, which the authors believe have a high potential as sulfur hosts in LSBs.
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000907456 7001_ $$0P:(DE-HGF)0$$aLiang, Zhifu$$b1
000907456 7001_ $$0P:(DE-Juel1)179016$$aTang, Pengyi$$b2
000907456 7001_ $$0P:(DE-HGF)0$$aZhang, Chaoqi$$b3
000907456 7001_ $$0P:(DE-HGF)0$$aTang, Mingxue$$b4
000907456 7001_ $$0P:(DE-HGF)0$$aLi, Qizhen$$b5
000907456 7001_ $$0P:(DE-HGF)0$$aBiendicho, Jordi Jacas$$b6
000907456 7001_ $$0P:(DE-HGF)0$$aLi, Junshan$$b7
000907456 7001_ $$0P:(DE-Juel1)130695$$aHeggen, Marc$$b8$$ufzj
000907456 7001_ $$0P:(DE-Juel1)144121$$aDunin-Borkowski, Rafal E.$$b9$$ufzj
000907456 7001_ $$0P:(DE-HGF)0$$aXu, Ming$$b10$$eCorresponding author
000907456 7001_ $$0P:(DE-HGF)0$$aLlorca, Jordi$$b11
000907456 7001_ $$0P:(DE-HGF)0$$aArbiol, Jordi$$b12$$eCorresponding author
000907456 7001_ $$0P:(DE-HGF)0$$aMorante, Joan Ramon$$b13
000907456 7001_ $$0P:(DE-HGF)0$$aChou, Shu-Lei$$b14$$eCorresponding author
000907456 7001_ $$0P:(DE-HGF)0$$aCabot, Andreu$$b15$$eCorresponding author
000907456 773__ $$0PERI:(DE-600)1474949-X$$a10.1002/adma.202108835$$gVol. 34, no. 10, p. 2108835 -$$n10$$p2108835 -$$tAdvanced materials$$v34$$x0935-9648$$y2022
000907456 8564_ $$uhttps://juser.fz-juelich.de/record/907456/files/Advanced%20Materials%20-%202022%20-%20Yang%20-%20A%20High%20Conductivity%201D%20d%20Conjugated%20Metal%20Organic%20Framework%20with%20Efficient%20Polysulfide-3.pdf
000907456 8564_ $$uhttps://juser.fz-juelich.de/record/907456/files/A%20High%20Conductivity-revised_all.pdf$$yPublished on 2022-03-10. Available in OpenAccess from 2023-03-10.
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