% IMPORTANT: The following is UTF-8 encoded.  This means that in the presence
% of non-ASCII characters, it will not work with BibTeX 0.99 or older.
% Instead, you should use an up-to-date BibTeX implementation like “bibtex8” or
% “biber”.

@ARTICLE{Yang:907456,
      author       = {Yang, Dawei and Liang, Zhifu and Tang, Pengyi and Zhang,
                      Chaoqi and Tang, Mingxue and Li, Qizhen and Biendicho, Jordi
                      Jacas and Li, Junshan and Heggen, Marc and Dunin-Borkowski,
                      Rafal E. and Xu, Ming and Llorca, Jordi and Arbiol, Jordi
                      and Morante, Joan Ramon and Chou, Shu-Lei and Cabot, Andreu},
      title        = {{A} {H}igh {C}onductivity 1{D} π–d {C}onjugated
                      {M}etal–{O}rganic {F}ramework with {E}fficient
                      {P}olysulfide {T}rapping‐{D}iffusion‐{C}atalysis in
                      {L}ithium–{S}ulfur {B}atteries},
      journal      = {Advanced materials},
      volume       = {34},
      number       = {10},
      issn         = {0935-9648},
      address      = {Weinheim},
      publisher    = {Wiley-VCH},
      reportid     = {FZJ-2022-02048},
      pages        = {2108835 -},
      year         = {2022},
      abstract     = {The shuttling behavior and sluggish conversion kinetics of
                      the intermediate lithium polysulfides (LiPS) represent the
                      main obstructions to the practical application of
                      lithium–sulfur batteries (LSBs). Herein, a 1D π–d
                      conjugated metal–organic framework (MOF), Ni-MOF-1D, is
                      presented as an efficient sulfur host to overcome these
                      limitations. Experimental results and density functional
                      theory calculations demonstrate that Ni-MOF-1D is
                      characterized by a remarkable binding strength for trapping
                      soluble LiPS species. Ni-MOF-1D also acts as an effective
                      catalyst for S reduction during the discharge process and
                      Li2S oxidation during the charging process. In addition, the
                      delocalization of electrons in the π–d system of
                      Ni-MOF-1D provides a superior electrical conductivity to
                      improve electron transfer. Thus, cathodes based on Ni-MOF-1D
                      enable LSBs with excellent performance, for example,
                      impressive cycling stability with over $82\%$ capacity
                      retention over 1000 cycles at 3 C, superior rate performance
                      of 575 mAh g−1 at 8 C, and a high areal capacity of 6.63
                      mAh cm−2 under raised sulfur loading of 6.7 mg cm−2. The
                      strategies and advantages here demonstrated can be extended
                      to a broader range of π–d conjugated MOFs materials,
                      which the authors believe have a high potential as sulfur
                      hosts in LSBs.},
      cin          = {ER-C-1},
      ddc          = {660},
      cid          = {I:(DE-Juel1)ER-C-1-20170209},
      pnm          = {5351 - Platform for Correlative, In Situ and Operando
                      Characterization (POF4-535) / ESTEEM3 - Enabling Science and
                      Technology through European Electron Microscopy (823717)},
      pid          = {G:(DE-HGF)POF4-5351 / G:(EU-Grant)823717},
      typ          = {PUB:(DE-HGF)16},
      UT           = {WOS:000747786300001},
      doi          = {10.1002/adma.202108835},
      url          = {https://juser.fz-juelich.de/record/907456},
}