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| Hauptseite > Publikationsdatenbank > A High Conductivity 1D π–d Conjugated Metal–Organic Framework with Efficient Polysulfide Trapping‐Diffusion‐Catalysis in Lithium–Sulfur Batteries > print |
| Hauptseite > Publikationsdatenbank > A High Conductivity 1D π–d Conjugated Metal–Organic Framework with Efficient Polysulfide Trapping‐Diffusion‐Catalysis in Lithium–Sulfur Batteries > print |
| 001 | 907456 | ||
| 005 | 20230522125346.0 | ||
| 024 | 7 | _ | |a 10.1002/adma.202108835 |2 doi |
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| 037 | _ | _ | |a FZJ-2022-02048 |
| 041 | _ | _ | |a English |
| 082 | _ | _ | |a 660 |
| 100 | 1 | _ | |a Yang, Dawei |0 0000-0002-3842-8286 |b 0 |
| 245 | _ | _ | |a A High Conductivity 1D π–d Conjugated Metal–Organic Framework with Efficient Polysulfide Trapping‐Diffusion‐Catalysis in Lithium–Sulfur Batteries |
| 260 | _ | _ | |a Weinheim |c 2022 |b Wiley-VCH |
| 336 | 7 | _ | |a article |2 DRIVER |
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| 336 | 7 | _ | |a Journal Article |0 0 |2 EndNote |
| 520 | _ | _ | |a The shuttling behavior and sluggish conversion kinetics of the intermediate lithium polysulfides (LiPS) represent the main obstructions to the practical application of lithium–sulfur batteries (LSBs). Herein, a 1D π–d conjugated metal–organic framework (MOF), Ni-MOF-1D, is presented as an efficient sulfur host to overcome these limitations. Experimental results and density functional theory calculations demonstrate that Ni-MOF-1D is characterized by a remarkable binding strength for trapping soluble LiPS species. Ni-MOF-1D also acts as an effective catalyst for S reduction during the discharge process and Li2S oxidation during the charging process. In addition, the delocalization of electrons in the π–d system of Ni-MOF-1D provides a superior electrical conductivity to improve electron transfer. Thus, cathodes based on Ni-MOF-1D enable LSBs with excellent performance, for example, impressive cycling stability with over 82% capacity retention over 1000 cycles at 3 C, superior rate performance of 575 mAh g−1 at 8 C, and a high areal capacity of 6.63 mAh cm−2 under raised sulfur loading of 6.7 mg cm−2. The strategies and advantages here demonstrated can be extended to a broader range of π–d conjugated MOFs materials, which the authors believe have a high potential as sulfur hosts in LSBs. |
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| 700 | 1 | _ | |a Liang, Zhifu |0 P:(DE-HGF)0 |b 1 |
| 700 | 1 | _ | |a Tang, Pengyi |0 P:(DE-Juel1)179016 |b 2 |
| 700 | 1 | _ | |a Zhang, Chaoqi |0 P:(DE-HGF)0 |b 3 |
| 700 | 1 | _ | |a Tang, Mingxue |0 P:(DE-HGF)0 |b 4 |
| 700 | 1 | _ | |a Li, Qizhen |0 P:(DE-HGF)0 |b 5 |
| 700 | 1 | _ | |a Biendicho, Jordi Jacas |0 P:(DE-HGF)0 |b 6 |
| 700 | 1 | _ | |a Li, Junshan |0 P:(DE-HGF)0 |b 7 |
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| 700 | 1 | _ | |a Dunin-Borkowski, Rafal E. |0 P:(DE-Juel1)144121 |b 9 |u fzj |
| 700 | 1 | _ | |a Xu, Ming |0 P:(DE-HGF)0 |b 10 |e Corresponding author |
| 700 | 1 | _ | |a Llorca, Jordi |0 P:(DE-HGF)0 |b 11 |
| 700 | 1 | _ | |a Arbiol, Jordi |0 P:(DE-HGF)0 |b 12 |e Corresponding author |
| 700 | 1 | _ | |a Morante, Joan Ramon |0 P:(DE-HGF)0 |b 13 |
| 700 | 1 | _ | |a Chou, Shu-Lei |0 P:(DE-HGF)0 |b 14 |e Corresponding author |
| 700 | 1 | _ | |a Cabot, Andreu |0 P:(DE-HGF)0 |b 15 |e Corresponding author |
| 773 | _ | _ | |a 10.1002/adma.202108835 |g Vol. 34, no. 10, p. 2108835 - |0 PERI:(DE-600)1474949-X |n 10 |p 2108835 - |t Advanced materials |v 34 |y 2022 |x 0935-9648 |
| 856 | 4 | _ | |u https://juser.fz-juelich.de/record/907456/files/Advanced%20Materials%20-%202022%20-%20Yang%20-%20A%20High%20Conductivity%201D%20d%20Conjugated%20Metal%20Organic%20Framework%20with%20Efficient%20Polysulfide-3.pdf |
| 856 | 4 | _ | |y Published on 2022-03-10. Available in OpenAccess from 2023-03-10. |u https://juser.fz-juelich.de/record/907456/files/A%20High%20Conductivity-revised_all.pdf |
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