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@ARTICLE{Frielinghaus:907461,
      author       = {Frielinghaus, H. and Fomina, M. and Hayward, D. and Dubey,
                      P. S. and Jaksch, S. and Falus, P. and Fouquet, P. and
                      Fruhner, L. and Holderer, O.},
      title        = {{I}onic {L}iquid ({E}mim{A}c)-{W}ater {M}ixture {C}onfined
                      in {N}anoporous {G}lass {M}atrices {S}tudied {W}ith
                      {H}igh-{R}esolution {N}eutron {S}pectroscopy},
      journal      = {Frontiers in physics},
      volume       = {10},
      issn         = {2296-424X},
      address      = {Lausanne},
      publisher    = {Frontiers Media},
      reportid     = {FZJ-2022-02052},
      pages        = {872616},
      year         = {2022},
      abstract     = {We report on the structure and diffusion behaviour of the
                      various constituent molecules in ionic liquid (IL) mixtures
                      under confinement in nanoporous glasses. X-Ray diffraction
                      measurements indicate that the ions adopt a lamellar
                      arrangement under confinement. Furthermore, using selective
                      deuteration in combination with high resolution neutron
                      spectroscopy reveals how the dynamics and the activation
                      energy of the IL is affected by different confinement
                      conditions (pore sizes 50 Å and 135 Å) and different
                      temperatures (265 and 318 K). With different deuteration
                      schemes we could separate the different motions of acetate
                      and water. The confinement leads to distortions of the
                      domains, which gives more room for diffusion. In the smaller
                      pores, the stronger distortion gives even more room such
                      that the hydrogen bonds between acetate and water seem to be
                      even stronger than in bulk and weaker confinement. The
                      results are discussed in the context of previous
                      measurements on dry samples.},
      cin          = {JCNS-FRM-II / MLZ / JCNS-1 / JCNS-4},
      ddc          = {530},
      cid          = {I:(DE-Juel1)JCNS-FRM-II-20110218 / I:(DE-588b)4597118-3 /
                      I:(DE-Juel1)JCNS-1-20110106 / I:(DE-Juel1)JCNS-4-20201012},
      pnm          = {6G4 - Jülich Centre for Neutron Research (JCNS) (FZJ)
                      (POF4-6G4) / 632 - Materials – Quantum, Complex and
                      Functional Materials (POF4-632)},
      pid          = {G:(DE-HGF)POF4-6G4 / G:(DE-HGF)POF4-632},
      experiment   = {EXP:(DE-MLZ)External-20140101},
      typ          = {PUB:(DE-HGF)16},
      UT           = {WOS:000811069800001},
      doi          = {10.3389/fphy.2022.872616},
      url          = {https://juser.fz-juelich.de/record/907461},
}