guest ::
| Home > Publications database > Ionic Liquid (EmimAc)-Water Mixture Confined in Nanoporous Glass Matrices Studied With High-Resolution Neutron Spectroscopy > print |
| Home > Publications database > Ionic Liquid (EmimAc)-Water Mixture Confined in Nanoporous Glass Matrices Studied With High-Resolution Neutron Spectroscopy > print |
| 001 | 907461 | ||
| 005 | 20240326211853.0 | ||
| 024 | 7 | _ | |a 10.3389/fphy.2022.872616 |2 doi |
| 024 | 7 | _ | |a 2128/31147 |2 Handle |
| 024 | 7 | _ | |a altmetric:127020773 |2 altmetric |
| 024 | 7 | _ | |a WOS:000811069800001 |2 WOS |
| 037 | _ | _ | |a FZJ-2022-02052 |
| 041 | _ | _ | |a English |
| 082 | _ | _ | |a 530 |
| 100 | 1 | _ | |a Frielinghaus, H. |0 P:(DE-Juel1)130646 |b 0 |e Corresponding author |u fzj |
| 245 | _ | _ | |a Ionic Liquid (EmimAc)-Water Mixture Confined in Nanoporous Glass Matrices Studied With High-Resolution Neutron Spectroscopy |
| 260 | _ | _ | |a Lausanne |c 2022 |b Frontiers Media |
| 336 | 7 | _ | |a article |2 DRIVER |
| 336 | 7 | _ | |a Output Types/Journal article |2 DataCite |
| 336 | 7 | _ | |a Journal Article |b journal |m journal |0 PUB:(DE-HGF)16 |s 1711444207_3379 |2 PUB:(DE-HGF) |
| 336 | 7 | _ | |a ARTICLE |2 BibTeX |
| 336 | 7 | _ | |a JOURNAL_ARTICLE |2 ORCID |
| 336 | 7 | _ | |a Journal Article |0 0 |2 EndNote |
| 520 | _ | _ | |a We report on the structure and diffusion behaviour of the various constituent molecules in ionic liquid (IL) mixtures under confinement in nanoporous glasses. X-Ray diffraction measurements indicate that the ions adopt a lamellar arrangement under confinement. Furthermore, using selective deuteration in combination with high resolution neutron spectroscopy reveals how the dynamics and the activation energy of the IL is affected by different confinement conditions (pore sizes 50 Å and 135 Å) and different temperatures (265 and 318 K). With different deuteration schemes we could separate the different motions of acetate and water. The confinement leads to distortions of the domains, which gives more room for diffusion. In the smaller pores, the stronger distortion gives even more room such that the hydrogen bonds between acetate and water seem to be even stronger than in bulk and weaker confinement. The results are discussed in the context of previous measurements on dry samples. |
| 536 | _ | _ | |a 6G4 - Jülich Centre for Neutron Research (JCNS) (FZJ) (POF4-6G4) |0 G:(DE-HGF)POF4-6G4 |c POF4-6G4 |f POF IV |x 0 |
| 536 | _ | _ | |a 632 - Materials – Quantum, Complex and Functional Materials (POF4-632) |0 G:(DE-HGF)POF4-632 |c POF4-632 |f POF IV |x 1 |
| 588 | _ | _ | |a Dataset connected to CrossRef, Journals: juser.fz-juelich.de |
| 650 | 2 | 7 | |a Soft Condensed Matter |0 V:(DE-MLZ)SciArea-210 |2 V:(DE-HGF) |x 0 |
| 650 | 1 | 7 | |a Energy |0 V:(DE-MLZ)GC-110 |2 V:(DE-HGF) |x 0 |
| 693 | _ | _ | |0 EXP:(DE-MLZ)External-20140101 |5 EXP:(DE-MLZ)External-20140101 |e Measurement at external facility |x 0 |
| 700 | 1 | _ | |a Fomina, M. |0 P:(DE-Juel1)185020 |b 1 |u fzj |
| 700 | 1 | _ | |a Hayward, D. |0 P:(DE-Juel1)185009 |b 2 |u fzj |
| 700 | 1 | _ | |a Dubey, P. S. |0 P:(DE-Juel1)188158 |b 3 |u fzj |
| 700 | 1 | _ | |a Jaksch, S. |0 P:(DE-Juel1)157910 |b 4 |u fzj |
| 700 | 1 | _ | |a Falus, P. |0 P:(DE-HGF)0 |b 5 |
| 700 | 1 | _ | |a Fouquet, P. |0 P:(DE-HGF)0 |b 6 |
| 700 | 1 | _ | |a Fruhner, L. |0 P:(DE-Juel1)169361 |b 7 |u fzj |
| 700 | 1 | _ | |a Holderer, O. |0 P:(DE-Juel1)130718 |b 8 |u fzj |
| 773 | _ | _ | |a 10.3389/fphy.2022.872616 |g Vol. 10, p. 872616 |0 PERI:(DE-600)2721033-9 |p 872616 |t Frontiers in physics |v 10 |y 2022 |x 2296-424X |
| 856 | 4 | _ | |u https://juser.fz-juelich.de/record/907461/files/188.pdf |y OpenAccess |
| 909 | C | O | |o oai:juser.fz-juelich.de:907461 |p openaire |p open_access |p OpenAPC |p driver |p VDB:MLZ |p VDB |p openCost |p dnbdelivery |
| 910 | 1 | _ | |a Forschungszentrum Jülich |0 I:(DE-588b)5008462-8 |k FZJ |b 0 |6 P:(DE-Juel1)130646 |
| 910 | 1 | _ | |a Forschungszentrum Jülich |0 I:(DE-588b)5008462-8 |k FZJ |b 1 |6 P:(DE-Juel1)185020 |
| 910 | 1 | _ | |a Forschungszentrum Jülich |0 I:(DE-588b)5008462-8 |k FZJ |b 2 |6 P:(DE-Juel1)185009 |
| 910 | 1 | _ | |a Forschungszentrum Jülich |0 I:(DE-588b)5008462-8 |k FZJ |b 3 |6 P:(DE-Juel1)188158 |
| 910 | 1 | _ | |a Forschungszentrum Jülich |0 I:(DE-588b)5008462-8 |k FZJ |b 4 |6 P:(DE-Juel1)157910 |
| 910 | 1 | _ | |a Forschungszentrum Jülich |0 I:(DE-588b)5008462-8 |k FZJ |b 7 |6 P:(DE-Juel1)169361 |
| 910 | 1 | _ | |a Forschungszentrum Jülich |0 I:(DE-588b)5008462-8 |k FZJ |b 8 |6 P:(DE-Juel1)130718 |
| 913 | 1 | _ | |a DE-HGF |b Forschungsbereich Materie |l Großgeräte: Materie |1 G:(DE-HGF)POF4-6G0 |0 G:(DE-HGF)POF4-6G4 |3 G:(DE-HGF)POF4 |2 G:(DE-HGF)POF4-600 |4 G:(DE-HGF)POF |v Jülich Centre for Neutron Research (JCNS) (FZJ) |x 0 |
| 913 | 1 | _ | |a DE-HGF |b Forschungsbereich Materie |l Von Materie zu Materialien und Leben |1 G:(DE-HGF)POF4-630 |0 G:(DE-HGF)POF4-632 |3 G:(DE-HGF)POF4 |2 G:(DE-HGF)POF4-600 |4 G:(DE-HGF)POF |v Materials – Quantum, Complex and Functional Materials |x 1 |
| 914 | 1 | _ | |y 2022 |
| 915 | p | c | |a Local Funding |0 PC:(DE-HGF)0001 |2 APC |
| 915 | p | c | |a DFG OA Publikationskosten |0 PC:(DE-HGF)0002 |2 APC |
| 915 | p | c | |a DOAJ Journal |0 PC:(DE-HGF)0003 |2 APC |
| 915 | _ | _ | |a DBCoverage |0 StatID:(DE-HGF)0160 |2 StatID |b Essential Science Indicators |d 2021-02-03 |
| 915 | _ | _ | |a Creative Commons Attribution CC BY 4.0 |0 LIC:(DE-HGF)CCBY4 |2 HGFVOC |
| 915 | _ | _ | |a WoS |0 StatID:(DE-HGF)0113 |2 StatID |b Science Citation Index Expanded |d 2021-02-03 |
| 915 | _ | _ | |a Fees |0 StatID:(DE-HGF)0700 |2 StatID |d 2021-02-03 |
| 915 | _ | _ | |a OpenAccess |0 StatID:(DE-HGF)0510 |2 StatID |
| 915 | _ | _ | |a Article Processing Charges |0 StatID:(DE-HGF)0561 |2 StatID |d 2021-02-03 |
| 915 | _ | _ | |a JCR |0 StatID:(DE-HGF)0100 |2 StatID |b FRONT PHYS-LAUSANNE : 2021 |d 2022-11-15 |
| 915 | _ | _ | |a DBCoverage |0 StatID:(DE-HGF)0200 |2 StatID |b SCOPUS |d 2022-11-15 |
| 915 | _ | _ | |a DBCoverage |0 StatID:(DE-HGF)0300 |2 StatID |b Medline |d 2022-11-15 |
| 915 | _ | _ | |a DBCoverage |0 StatID:(DE-HGF)0501 |2 StatID |b DOAJ Seal |d 2021-05-12T10:34:55Z |
| 915 | _ | _ | |a DBCoverage |0 StatID:(DE-HGF)0500 |2 StatID |b DOAJ |d 2021-05-12T10:34:55Z |
| 915 | _ | _ | |a Peer Review |0 StatID:(DE-HGF)0030 |2 StatID |b DOAJ : Blind peer review |d 2021-05-12T10:34:55Z |
| 915 | _ | _ | |a DBCoverage |0 StatID:(DE-HGF)0199 |2 StatID |b Clarivate Analytics Master Journal List |d 2022-11-15 |
| 915 | _ | _ | |a DBCoverage |0 StatID:(DE-HGF)0150 |2 StatID |b Web of Science Core Collection |d 2022-11-15 |
| 915 | _ | _ | |a DBCoverage |0 StatID:(DE-HGF)1150 |2 StatID |b Current Contents - Physical, Chemical and Earth Sciences |d 2022-11-15 |
| 915 | _ | _ | |a IF < 5 |0 StatID:(DE-HGF)9900 |2 StatID |d 2022-11-15 |
| 920 | _ | _ | |l yes |
| 920 | 1 | _ | |0 I:(DE-Juel1)JCNS-FRM-II-20110218 |k JCNS-FRM-II |l JCNS-FRM-II |x 0 |
| 920 | 1 | _ | |0 I:(DE-588b)4597118-3 |k MLZ |l Heinz Maier-Leibnitz Zentrum |x 1 |
| 920 | 1 | _ | |0 I:(DE-Juel1)JCNS-1-20110106 |k JCNS-1 |l Neutronenstreuung |x 2 |
| 920 | 1 | _ | |0 I:(DE-Juel1)JCNS-4-20201012 |k JCNS-4 |l JCNS-4 |x 3 |
| 980 | _ | _ | |a journal |
| 980 | _ | _ | |a VDB |
| 980 | _ | _ | |a I:(DE-Juel1)JCNS-FRM-II-20110218 |
| 980 | _ | _ | |a I:(DE-588b)4597118-3 |
| 980 | _ | _ | |a I:(DE-Juel1)JCNS-1-20110106 |
| 980 | _ | _ | |a I:(DE-Juel1)JCNS-4-20201012 |
| 980 | _ | _ | |a APC |
| 980 | _ | _ | |a UNRESTRICTED |
| 980 | 1 | _ | |a APC |
| 980 | 1 | _ | |a FullTexts |
| Library | Collection | CLSMajor | CLSMinor | Language | Author |
|---|