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@ARTICLE{Herrmann:907623,
      author       = {Herrmann, Christoph and Raths, Miriam and Kumpf, Christian
                      and Kavanagh, Karen L.},
      title        = {{R}otational epitaxy of h-{BN} on {C}u (110)},
      journal      = {Surface science},
      volume       = {721},
      issn         = {0039-6028},
      address      = {Amsterdam},
      publisher    = {Elsevier},
      reportid     = {FZJ-2022-02112},
      pages        = {122080 -},
      year         = {2022},
      abstract     = {The growth of wafer-scale, single-crystalline hexagonal
                      boron nitride (h-BN) monolayers on catalytic metallic
                      substrates, requires a sparse nucleation density. At high
                      temperatures ( C), preparation of vicinal Cu (110) with
                      annealing is reported to provide preferential nucleation of
                      single antiphase domains of h-BN with facets parallel to Cu
                      steps. We have used in situ low-energy electron microscopy
                      (LEEM) to image nucleation and growth of h-BN islands on a
                      Cu (110) single crystal at lower temperatures (650–750)C.
                      With annealing, diffraction (LEED) and dark field imaging
                      (LEEM) confirmed the formation of three sets of h-BN
                      antiphase domains. Two sets are epitaxially aligned with
                      four Cu in-plane directions, the lowest lattice mismatch
                      available. While alignment is excellent in one direction,
                      the other trigonal directions are 10.4 rotationally
                      mismatched. A third pair of antiphase domains nucleates
                      aligned with in-plane directions. These domains are midway,
                      rotated 5.2 with respect to either type of domain, and have
                      the lowest interfacial energy. Localized defects were found
                      to correlate with every island nucleation event.},
      cin          = {PGI-3},
      ddc          = {530},
      cid          = {I:(DE-Juel1)PGI-3-20110106},
      pnm          = {5213 - Quantum Nanoscience (POF4-521)},
      pid          = {G:(DE-HGF)POF4-5213},
      typ          = {PUB:(DE-HGF)16},
      UT           = {WOS:000912772700001},
      doi          = {10.1016/j.susc.2022.122080},
      url          = {https://juser.fz-juelich.de/record/907623},
}